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{:(,"Column I",,"Column II"),((a),[Pt(NH...

`{:(,"Column I",,"Column II"),((a),[Pt(NH_(3))ClBrI]^(-),(p),"Square planar"),((b),[Pt(NH_(3))ClBrNO_(2)]^(-),(q),EAN=84),((c),[Pt(NH_(3))Cl(CN)_(2)]^(-),(r),"Linkage isomers are 3"),(,,(t),"Linkage isomers are 4"):}`

Text Solution

Verified by Experts

The correct Answer is:
(a-p,q);(b-p,q,s);(c-p,q,r);(d-p,q,t)
EAN=78-2+8=84. All `Pt^(2+)` complexes are square planar
(b) `NO_(2)`,-ONO (Linkage)
(c ) (C,C), (C,N),(N,N) (Linkage)
(d) `C_(3),C_(2),N,CN_(2),N_(3)` (Linkage)
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There are some coordination compounds given in column-I which may exist in different isomeric forms as given in column-II.Select the option for the coordination compounds and their respective isomeric forms. {:("Column-I","Column-II"),((A)[Co(en)_2NH_3Cl]SO_4,(p)"Optical isomer"),((B)[Co(NH_3)_4(NO_2)_2](NO_3),(q)"Geometrical isomer"),((C)[Co(en)(pn)(NO_2)_2]Cl,(r)"Ionization isomer"),((D )[Co(gly)_3], (s)"Linkage isomer"),(" " , (t)"Hydrate isomer"):}

Write IUPAC name for [Pt(NH_(3))_(2)Cl_(4)]^(2-) .

Knowledge Check

  • [Pt(NH_3)_4]CL_2 is

    A
    pyramidal
    B
    pentagonal
    C
    tetrahedral
    D
    square planar

  • EAN of Pt in [Pt(NH_(3))_(4)]^(2+)

    A
    35
    B
    40
    C
    80
    D
    84

  • The EAN of Pt in [Pt(NH_(3))_(4)]^(2+)

    A
    33
    B
    34
    C
    35
    D
    36

    • Similar Questions

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    Write the IUPAC names of i) [Cr(NH_(3))_(4)Cl_(2)]^(2-) ii) [Pt(NH_(3))_(2)Cl_(2)]Cl_(2)

    For the square planar complex [Pt(NH_(3))_(4)(NH_(2)OH)py(No_(2))]^(o+) how many geometrical isomers are possible .

    [Pt(NH_(3))(NO_(2))Ph(NH_(2)OH)]^(+) , the no. of geometrical isomers including linkage isomerism is

    {:("Compound",,,,"Total stereoisomer"),((A)[Co(en)_(2)Cl]^(+),,,,(P)2),((B)[Co(en)_(3)]Cl_(3),,,,(Q)3),((C)[Pt(NH_(3))_(2)Cl_(2)],,,,(R)4),((D)[Pt(NH_(3))_(3)Cl_(3)]^(+),,,,(S)5):} Correct code :-

    [Pt(NH_(3))(NH_(2)OH)(NO_(2))(py)]^(+) will form how many geometrical isomers ?

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