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{:(,"Column I",,"Column II"),((a),[Pt(NH...

`{:(,"Column I",,"Column II"),((a),[Pt(NH_(3))ClBrI]^(-),(p),"Square planar"),((b),[Pt(NH_(3))ClBrNO_(2)]^(-),(q),EAN=84),((c),[Pt(NH_(3))Cl(CN)_(2)]^(-),(r),"Linkage isomers are 3"),(,,(t),"Linkage isomers are 4"):}`

Text Solution

Verified by Experts

The correct Answer is:
(a-p,q);(b-p,q,s);(c-p,q,r);(d-p,q,t)

EAN=78-2+8=84. All `Pt^(2+)` complexes are square planar
(b) `NO_(2)`,-ONO (Linkage)
(c ) (C,C), (C,N),(N,N) (Linkage)
(d) `C_(3),C_(2),N,CN_(2),N_(3)` (Linkage)
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Knowledge Check

  • [Pt(NH_3)_4]CL_2 is

    A
    pyramidal
    B
    pentagonal
    C
    tetrahedral
    D
    square planar
  • EAN of Pt in [Pt(NH_(3))_(4)]^(2+)

    A
    35
    B
    40
    C
    80
    D
    84
  • The EAN of Pt in [Pt(NH_(3))_(4)]^(2+)

    A
    33
    B
    34
    C
    35
    D
    36