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The denticity of the ligand N(CH(2)CH(2)...

The denticity of the ligand `N(CH_(2)CH_(2)NH_(2))_(3)` is

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To determine the denticity of the ligand \( N(CH_2CH_2NH_2)_3 \), we will analyze its structure and identify the number of donor atoms that can coordinate with a metal ion. ### Step-by-Step Solution: 1. **Identify the Structure of the Ligand**: The ligand \( N(CH_2CH_2NH_2)_3 \) consists of a central nitrogen atom bonded to three ethylene diamine groups (each containing an amino group, \( NH_2 \)). 2. **Identify the Donor Atoms**: Each ethylene diamine group has two nitrogen atoms that can donate lone pairs to a metal ion. Since there are three such groups, we need to count the total number of nitrogen donor atoms. 3. **Count the Nitrogen Atoms**: - Each of the three ethylene diamine groups contributes two nitrogen atoms. - Therefore, the total number of nitrogen atoms is: \[ 3 \text{ groups} \times 2 \text{ nitrogen atoms/group} = 6 \text{ nitrogen atoms} \] 4. **Determine the Denticity**: The denticity of a ligand is defined as the number of donor atoms that can coordinate to a central metal ion. In this case, since there are 6 nitrogen atoms that can coordinate with the metal ion, the denticity of the ligand \( N(CH_2CH_2NH_2)_3 \) is 6. ### Final Answer: The denticity of the ligand \( N(CH_2CH_2NH_2)_3 \) is **6**.

To determine the denticity of the ligand \( N(CH_2CH_2NH_2)_3 \), we will analyze its structure and identify the number of donor atoms that can coordinate with a metal ion. ### Step-by-Step Solution: 1. **Identify the Structure of the Ligand**: The ligand \( N(CH_2CH_2NH_2)_3 \) consists of a central nitrogen atom bonded to three ethylene diamine groups (each containing an amino group, \( NH_2 \)). 2. **Identify the Donor Atoms**: ...
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The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be simple ions such as Cl^(-) , small molecules such as H_(2)O or NH_(3) , larger molecules such as H_(2)NCH_(2)CH_(2)NH_(2) or N(CH_(2)CH_(2)NH_(2))_(3) or even macromolecules, such as proteins. When a ligand is bound to a metal ion through a single donor atom, as with Cl^(-), H_(2)O or NH_(3) , the ligand is said to be unidentate. When a ligand can bind through two donor atoms as in H_(2)NCH_(2)CH_(2)NH_(2) (ethane-1, 2-diamine) or C_(2)O_(4)^(2-) (oxalate), the ligand is said to be didentate and when several donor atoms are present in single ligand as in N(CH_(2)CH_(2)NH_(2))_(3) , the ligand is said to be polydentate Ethylenediamineteraacetate ion [EDTA^(4-)] is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion. What type of ligands are H_(2)O and NH_(3) ?

The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be simple ions such as Cl^(-) , small molecules such as H_(2)O or NH_(3) , larger molecules such as H_(2)NCH_(2)CH_(2)NH_(2) or N(CH_(2)CH_(2)NH_(2))_(3) or even macromolecules, such as proteins. When a ligand is bound to a metal ion through a single donor atom, as with Cl^(-), H_(2)O or NH_(3) , the ligand is said to be unidentate. When a ligand can bind through two donor atoms as in H_(2)NCH_(2)CH_(2)NH_(2) (ethane-1, 2-diamine) or C_(2)O_(4)^(2-) (oxalate), the ligand is said to be didentate and when several donor atoms are present in single ligand as in N(CH_(2)CH_(2)NH_(2))_(3) , the ligand is said to be polydentate Ethylenediamineteraacetate ion [EDTA^(4-)] is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion. What is meant by didentate ligand ? Give an example other than ethane-1,2-diamine.

Knowledge Check

  • The correct decreasing priority of ligands -NO_(2),-C-=N,NH_(2) and -CH_(2)NH_(2) in absolute sonfiguration of an enentiomer is : \

    A
    `NO_(2)gtNH_(2)gtC-=NgtCH_(2)NH_(2)`
    B
    `NO_(2)gtC-=NgtNH_(2)gtCH_(2)gtNH_(2)`
    C
    `NH_(2)gtNOgtC-=NgtCH_(2)NH_(2)`
    D
    `NH_(2)gtNO_(2)gtCH_(2)NH_(2)gtV-=N`
  • Arrange the following in decreasing order of the basicity. CH_(2)=CHCH_(2)NH_(2),CH_(3)CH_(2)CH_(2)NH_(2),CH-=C CH_(2)NH_(2)

    A
    `IgtIIgtIII`
    B
    `IIgtIgtIII`
    C
    `IIIgtIIgtI`
    D
    `IIgtIIIgtI`
  • The correct order of increasing basic nature of the bases NH_(3),CH_(2)NH_(2) and (CH_(3))_(2)NH is-

    A
    `CH_(3)NH_(2) lt NH_(3)(CH_(3))_(2)NH`
    B
    `(CH_(3))_(2)NHltNH_(3)ltCH_(3)NH_(2)`
    C
    `NH_(3) lt CH_(3)NH_(2)lt(CH_(3))_(2)NH`
    D
    `CH_(3)NH_(2)lt(CH_(3))_(2)NHltNH`
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    The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be simple ions such as Cl^(-) , small molecules such as H_(2)O or NH_(3) , larger molecules such as H_(2)NCH_(2)CH_(2)NH_(2) or N(CH_(2)CH_(2)NH_(2))_(3) or even macromolecules, such as proteins. When a ligand is bound to a metal ion through a single donor atom, as with Cl^(-), H_(2)O or NH_(3) , the ligand is said to be unidentate. When a ligand can bind through two donor atoms as in H_(2)NCH_(2)CH_(2)NH_(2) (ethane-1, 2-diamine) or C_(2)O_(4)^(2-) (oxalate), the ligand is said to be didentate and when several donor atoms are present in single ligand as in N(CH_(2)CH_(2)NH_(2))_(3) , the ligand is said to be polydentate Ethylenediamineteraacetate ion [EDTA^(4-)] is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion. How many nitrogen atoms and oxygen atoms in ethylenediaminetetraacetate are bonded to the metal in the complex compounds ?

    The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be simple ions such as Cl^(-) , small molecules such as H_(2)O or NH_(3) , larger molecules such as H_(2)NCH_(2)CH_(2)NH_(2) or N(CH_(2)CH_(2)NH_(2))_(3) or even macromolecules, such as proteins. When a ligand is bound to a metal ion through a single donor atom, as with Cl^(-), H_(2)O or NH_(3) , the ligand is said to be unidentate. When a ligand can bind through two donor atoms as in H_(2)NCH_(2)CH_(2)NH_(2) (ethane-1, 2-diamine) or C_(2)O_(4)^(2-) (oxalate), the ligand is said to be didentate and when several donor atoms are present in single ligand as in N(CH_(2)CH_(2)NH_(2))_(3) , the ligand is said to be polydentate Ethylenediamineteraacetate ion [EDTA^(4-)] is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion. Write the formula of ethylenediamine.

    The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be simple ions such as Cl^(-) , small molecules such as H_(2)O or NH_(3) , larger molecules such as H_(2)NCH_(2)CH_(2)NH_(2) or N(CH_(2)CH_(2)NH_(2))_(3) or even macromolecules, such as proteins. When a ligand is bound to a metal ion through a single donor atom, as with Cl^(-), H_(2)O or NH_(3) , the ligand is said to be unidentate. When a ligand can bind through two donor atoms as in H_(2)NCH_(2)CH_(2)NH_(2) (ethane-1, 2-diamine) or C_(2)O_(4)^(2-) (oxalate), the ligand is said to be didentate and when several donor atoms are present in single ligand as in N(CH_(2)CH_(2)NH_(2)_(3) , the ligand is said to be polydentate Ethylenediamineteraacetate ion [EDTA^(4-)] is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion. What is meant by the term ligand ?

    CH_(3)CH_(2)NH_(2) is soluble in :-

    Arrange the basic strength of the following compounds. (i) CH_(2) = CHCH_(2)NH_(2) (ii) CH_(3)CH_(2)CH_(2)NH_(2) (iii) CH -= C - CH_(2)NH_(2)