The denticity of the ligand `N(CH_(2)CH_(2)NH_(2))_(3)` is
The denticity of the ligand `N(CH_(2)CH_(2)NH_(2))_(3)` is
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The correct Answer is:
To determine the denticity of the ligand \( N(CH_2CH_2NH_2)_3 \), we will analyze its structure and identify the number of donor atoms that can coordinate with a metal ion.
### Step-by-Step Solution:
1. **Identify the Structure of the Ligand**:
The ligand \( N(CH_2CH_2NH_2)_3 \) consists of a central nitrogen atom bonded to three ethylene diamine groups (each containing an amino group, \( NH_2 \)).
2. **Identify the Donor Atoms**:
Each ethylene diamine group has two nitrogen atoms that can donate lone pairs to a metal ion. Since there are three such groups, we need to count the total number of nitrogen donor atoms.
3. **Count the Nitrogen Atoms**:
- Each of the three ethylene diamine groups contributes two nitrogen atoms.
- Therefore, the total number of nitrogen atoms is:
\[
3 \text{ groups} \times 2 \text{ nitrogen atoms/group} = 6 \text{ nitrogen atoms}
\]
4. **Determine the Denticity**:
The denticity of a ligand is defined as the number of donor atoms that can coordinate to a central metal ion. In this case, since there are 6 nitrogen atoms that can coordinate with the metal ion, the denticity of the ligand \( N(CH_2CH_2NH_2)_3 \) is 6.
### Final Answer:
The denticity of the ligand \( N(CH_2CH_2NH_2)_3 \) is **6**.
To determine the denticity of the ligand \( N(CH_2CH_2NH_2)_3 \), we will analyze its structure and identify the number of donor atoms that can coordinate with a metal ion.
### Step-by-Step Solution:
1. **Identify the Structure of the Ligand**:
The ligand \( N(CH_2CH_2NH_2)_3 \) consists of a central nitrogen atom bonded to three ethylene diamine groups (each containing an amino group, \( NH_2 \)).
2. **Identify the Donor Atoms**:
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The ions or molecules bound to the central atom/ion in the coordination entity are called ligands. These may be simple ions such as Cl^(-) , small molecules such as H_(2)O or NH_(3) , larger molecules such as H_(2)NCH_(2)CH_(2)NH_(2) or N(CH_(2)CH_(2)NH_(2))_(3) or even macromolecules, such as proteins. When a ligand is bound to a metal ion through a single donor atom, as with Cl^(-), H_(2)O or NH_(3) , the ligand is said to be unidentate. When a ligand can bind through two donor atoms as in H_(2)NCH_(2)CH_(2)NH_(2) (ethane-1, 2-diamine) or C_(2)O_(4)^(2-) (oxalate), the ligand is said to be didentate and when several donor atoms are present in single ligand as in N(CH_(2)CH_(2)NH_(2))_(3) , the ligand is said to be polydentate Ethylenediamineteraacetate ion [EDTA^(4-)] is an important hexadentate ligand. It can bind through two nitrogen and four oxygen atoms to a central metal ion. What type of ligands are H_(2)O and NH_(3) ?
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Knowledge Check
The correct decreasing priority of ligands -NO_(2),-C-=N,NH_(2) and -CH_(2)NH_(2) in absolute sonfiguration of an enentiomer is : \
The correct decreasing priority of ligands -NO_(2),-C-=N,NH_(2) and -CH_(2)NH_(2) in absolute sonfiguration of an enentiomer is : \
A
`NO_(2)gtNH_(2)gtC-=NgtCH_(2)NH_(2)`
B
`NO_(2)gtC-=NgtNH_(2)gtCH_(2)gtNH_(2)`
C
`NH_(2)gtNOgtC-=NgtCH_(2)NH_(2)`
D
`NH_(2)gtNO_(2)gtCH_(2)NH_(2)gtV-=N`
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D
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A
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B
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C
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