Answer the questions (given below) which are based on the following diagram. Vapour pressure plots of benzene-toluence mixture at `20^(@)C`. Solution of benzene and toluence are ideal. Raoult's law is valid for both components over the entrie range of concentration.
An ideal solution consisting of two components A and B (such as benzene and toluence) is one in whic:
Answer the questions (given below) which are based on the following diagram. Vapour pressure plots of benzene-toluence mixture at `20^(@)C`. Solution of benzene and toluence are ideal. Raoult's law is valid for both components over the entrie range of concentration.
An ideal solution consisting of two components A and B (such as benzene and toluence) is one in whic:
An ideal solution consisting of two components A and B (such as benzene and toluence) is one in whic:
A
the intermolecular attraction A...A, B...B and A...B are equal
B
`DeltaH_(mix) = 0, DeltaV_(mix) = 0`
C
both of the above conditions are followed
D
none of the above conditions are followed
Text Solution
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The correct Answer is:
C
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Answer the questions (given below) which are based on the following diagram: vapour pessure diagram for real solution of two liquids A and B that exhibit a negative deviation from Raoult's law. The vapour pressure of both A and B are less than predicted by Raoult's law. The dashed lines represent the plots for ideal solutions. Solution containing components A and B show this type of deviation from ideal behaviour when:
An ideal solution follows Raoult's law over all ranges of concentrations and pressure.
Consider the following partially labelled figure (graph is upto scale) for an ideal binary solution of benzene and toluence and answer the following questions. Which graph corresponds to benzene ?
Consider the following partially labelled figure (graph is upto scale) for an ideal binary solution of benzene and toluence and answer the following questions.
Benzene and toluene form nearly ideal solutions.At 20^@C , the vapour pressure of benzene is 75 torr. The partial vapour pressure of benzene at 20^@C for a solution containing 78g benzene and 46g touene is torr is
Benzene and toluene form nearly ideal solutions. At 20^(@) C, the vapour pressure of benzene is 75 torr. The partial vapour pressure of benzene at 20^(@) C for a solution containing 78 g of benzene and 46 g of toluene in torr is :
Answer the question (given below) which are based on the following diagra. Consider some facts about the above phase diagram : Vapour pressure diagram for real solutions of two liquids A and B that exhibit a positive deviation from Raoult's law. The vapour pressure of both A and B are greater than predicted by Raoult's law. The dashed lines lines represented the plots for ideal solutions. Total vapour pressure of mixture of 1 mol of volatile component A(P_(A)^(@)=100 mmHg) and 3 mol of volatile component B(P_(B)^(@)=60 mmHg) is 75 mm . For such case:
Answer the question (given below) which are based on the following diagra. Consider some facts about the above phase diagram : Vapour pressure diagram for real solutions of two liquids A and B that exhibit a positive deviation from Raoult's law. The vapour pressure of both A and B are greater than predicted by Raoult's law. The dashed lines lines represented the plots for ideal solutions. A : This is observed when A...B attraction are greater than average of A...B and B...B attraction: B : DeltaH_("mix")=+ve,DeltaV_("mix")=+ve C : Boiling point is smaller than expected such that vaporisation is increased D : Mixture is called azeotropic mixture Select correct facts
Answer the questions (given below) which are based on the following diagram ? Consider some facts about the above phase diagram. Vapour pressure diagram for real solutions of two liquids A and B that exhibit a positive deviation from Raoult's law. The vapour presssure of both A and B are greater than predicted by Raoult's law. The dashed lines represented the plots for ideal solutions. A : This is obserbed when A...B attractions are greater than average of A...B and B.....B attraction : B : DeltaH_(mix) = +ve, DeltaV_(mix) = +ve C : Boiling point is smaller than expected such that vaporisation is increased D : Mixture can from azeotropic mixture Select correct facts.
Knowledge Check
Answer the questions (given below) which are based on the following diagram. Vapour pressure plots of benzene-toluence mixture at 20^(@)C . Solution of benzene and toluence are ideal. Raoult's law is valid for both components over the entrie range of concentration. There is deviation from ideal behaviour if mixture contains:
Answer the questions (given below) which are based on the following diagram. Vapour pressure plots of benzene-toluence mixture at 20^(@)C . Solution of benzene and toluence are ideal. Raoult's law is valid for both components over the entrie range of concentration. There is deviation from ideal behaviour if mixture contains:
A
n-hexane and n-heptane
B
chlorobenzene and bromobenzene
C
o-xylene and p-xylene
D
acetone and chloroform
Answer the questions (given below) which are based on the following diagram: vapour pessure diagram for real solution of two liquids A and B that exhibit a negative deviation from Raoult's law. The vapour pressure of both A and B are less than predicted by Raoult's law. The dashed lines represent the plots for ideal solutions. Solution containing components A and B show this type of deviation from ideal behaviour when:
Answer the questions (given below) which are based on the following diagram: vapour pessure diagram for real solution of two liquids A and B that exhibit a negative deviation from Raoult's law. The vapour pressure of both A and B are less than predicted by Raoult's law. The dashed lines represent the plots for ideal solutions. Solution containing components A and B show this type of deviation from ideal behaviour when:
A
`{:("Attraction" A...B,DeltaH_("mix"),DeltaV_("mix"),B.P),("Larger than average of" A...A .B..B"attraction",+ve,+ve,"larger than expected"):}`
B
`{:("Attraction" A...B,DeltaH_("mix"),DeltaV_("mix"),B.P),("As in" (a),-ve,-ve,"As in" (a)):}`
C
`{:("Attraction" A...B,DeltaH_("mix"),DeltaV_("mix"),B.P),("Smaller than average of" A...A..B..B "attraction",+ve,+ve,"Smaller than expected"):}`
D
`{:("Attraction" A...B,DeltaH_("mix"),DeltaV_("mix"),B.P),("As in"(c),-ve,-ve,"As in"(c)):}`
Consider the following partially labelled figure (graph is upto scale) for an ideal binary solution of benzene and toluence and answer the following questions. Which graph corresponds to benzene ?
Consider the following partially labelled figure (graph is upto scale) for an ideal binary solution of benzene and toluence and answer the following questions. Which graph corresponds to benzene ?
A
1
B
2
C
3
D
Any of 1 or 2