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Solubility of alkaline earth metal sulph...

Solubility of alkaline earth metal sulphates decreases down the group 2 because

A

they become more ionic

B

lattica energy of sulphates does not vary siginifacantly

C

hydration energy decreases rapidly from `Be^(2+)` to `Ba^(2+)`

D

latica energy plays more predominant role than hydration energy

Text Solution

Verified by Experts

The correct Answer is:
c

Duet to very large size of sulphate ions, the magnitude of lattice energy of alkaline earth metal sulphates remains almost constant. Thus, their solubility is only govermed by hydration energy which decreases from `Be^(2+)` to `Ba^(2+)`
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Knowledge Check

  • A : Solubility of alkaline earth metal carbonates decreases down the group. R : Hydration enthalpy decreases down the group whereas lattice enthalpy remain almost constant

    A
    If both Assertion & Reason are true and the reason is the correct explanantion of the assertion, then mark (1).
    B
    If both Assertion & Reason are true and the reason is not the correct explanantion of the assertion, then mark (2).
    C
    If Assertion is true statement but Reason is false. Them mark (3).
    D
    If both Assertion and reason are false statement, then mark (4).
  • The solubility of sulphates of alkaline earth metals in water decreases down the group because

    A
    The lattice energy of sulphates of group II decreases down the group
    B
    The lattice energy of sulphates of group II increases down the group
    C
    Both hydration and lattice energies decreases down the group
    D
    The decrease in hydration energy is more than the decreases in lattice energy
  • Solubility of the alkaline earth.s metal sulphates in decreases in the sequences

    A
    `CagtSrgtBagtMg`
    B
    `SrgtCagtMg gtBa`
    C
    `Bagtmg gt Sr gt Ca`
    D
    `Mg gt Ca gt Sr gt Ba`
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