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The secondary valency of chromium in [Cr...

The secondary valency of chromium in `[Cr(en)_(3)]Cl_(3)` is

A

`6`

B

`3`

C

`2`

D

`4`

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The correct Answer is:
To determine the secondary valency of chromium in the complex `[Cr(en)_(3)]Cl_(3)`, we can follow these steps: ### Step 1: Identify the Coordination Complex The given complex is `[Cr(en)_(3)]Cl_(3)`. Here, `Cr` represents chromium, and `en` stands for ethylenediamine, which is a bidentate ligand. ### Step 2: Understand the Ligands Ethylenediamine (en) is a bidentate ligand, meaning that each en molecule can form two bonds with the chromium ion. Since there are three en ligands in the complex, we need to calculate the total number of bonds formed. ### Step 3: Calculate the Total Number of Bonds Since each bidentate ligand (en) forms two bonds with the metal center (Cr), and there are three such ligands, the total number of bonds formed is: \[ \text{Total Bonds} = \text{Number of Ligands} \times \text{Bonds per Ligand} = 3 \times 2 = 6 \] ### Step 4: Determine the Secondary Valency The secondary valency is defined as the total number of bonds formed by the metal with the ligands. In this case, since we calculated that there are 6 bonds formed by the three bidentate en ligands, the secondary valency of chromium in `[Cr(en)_(3)]Cl_(3)` is 6. ### Conclusion Thus, the secondary valency of chromium in the complex `[Cr(en)_(3)]Cl_(3)` is **6**. ---

To determine the secondary valency of chromium in the complex `[Cr(en)_(3)]Cl_(3)`, we can follow these steps: ### Step 1: Identify the Coordination Complex The given complex is `[Cr(en)_(3)]Cl_(3)`. Here, `Cr` represents chromium, and `en` stands for ethylenediamine, which is a bidentate ligand. ### Step 2: Understand the Ligands Ethylenediamine (en) is a bidentate ligand, meaning that each en molecule can form two bonds with the chromium ion. Since there are three en ligands in the complex, we need to calculate the total number of bonds formed. ...
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The sum of primary and secondary valencies of chromium in the complex CrBr_(3).6NH_(3) is .

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Knowledge Check

  • The oxidation state of chromium is [Cr(PPh_(3))_(3)] is

    A
    `+3`
    B
    `+8`
    C
    `0`
    D
    `+5`
  • The oxidation state of chromium in [Cr(PPh_3)_3(CO)] is

    A
    `+3`
    B
    `+8`
    C
    5
    D
    6
  • The hybridization of Cr in [Cr(en)_(3)]^(3+) is

    A
    `d^(2)sp^(3)`
    B
    `sp^(3)d`
    C
    `sp^(3)d^(2)`
    D
    `dsp^(3)`
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