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An ambidentate ligand is one which...

An ambidentate ligand is one which

A

is linkage to the metal atom at two points

B

has two donor atoms but only one of them has the capacity to form a coordinate bond

C

has two donor atoms but either of the two can form a co-ordinate bond

D

forms chelate rings

Text Solution

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The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding Ambidentate Ligands**: An ambidentate ligand is a type of ligand that has two different donor atoms, but it can bind to the metal center through only one of those atoms at a time. This means that while the ligand has multiple potential binding sites, it does not bind through both simultaneously. 2. **Analyzing the Options**: - **Option 1**: "Links to the metal at two points." This is incorrect because an ambidentate ligand does not bind at two points simultaneously; it binds at one point at a time. - **Option 2**: "Has two donor atoms, but only one of them has the capacity to form a coordinate bond." This is also incorrect because both donor atoms can form coordinate bonds, but only one can do so at a time. - **Option 3**: "Has two donor atoms, either of which can form a coordinate bond." This is correct. An ambidentate ligand has two donor atoms, and it can bind through either one, but not both at the same time. - **Option 4**: "Forms chelate rings." This is incorrect because chelate formation typically involves bidentate or polydentate ligands that can bind through multiple sites simultaneously, forming ring structures. 3. **Conclusion**: The correct definition of an ambidentate ligand is given in **Option 3**: "Has two donor atoms, either of which can form a coordinate bond." **Final Answer**: An ambidentate ligand is one that has two donor atoms, either of which can form a coordinate bond. ---

**Step-by-Step Solution:** 1. **Understanding Ambidentate Ligands**: An ambidentate ligand is a type of ligand that has two different donor atoms, but it can bind to the metal center through only one of those atoms at a time. This means that while the ligand has multiple potential binding sites, it does not bind through both simultaneously. 2. **Analyzing the Options**: - **Option 1**: "Links to the metal at two points." This is incorrect because an ambidentate ligand does not bind at two points simultaneously; it binds at one point at a time. - **Option 2**: "Has two donor atoms, but only one of them has the capacity to form a coordinate bond." This is also incorrect because both donor atoms can form coordinate bonds, but only one can do so at a time. - **Option 3**: "Has two donor atoms, either of which can form a coordinate bond." This is correct. An ambidentate ligand has two donor atoms, and it can bind through either one, but not both at the same time. ...
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Name the type of isomerism when ambidentate ligands are attached to control metal ion. Give two examples of ambidentate ligands.

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Knowledge Check

  • An ambidentate ligand in one which

    A
    is linked to the metal atom through two donor atoms
    B
    has two donor atoms, but only one of them has the capacity to form a coordinate bond [or a sigma `(sigma)` bond]
    C
    has two donor atoms, but either of two can form a coordinate bond
    D
    form chelate rings.
  • A ambidentate ligand is one which -

    A
    is linked to the metal atom at two points
    B
    has two donor atoms at two points
    C
    has two donor atoms but either of the two can form a co - ordinate bond
    D
    forms chelate rings
  • An ambident ligand is one which

    A
    is linked to the metal atom through two donor atoms
    B
    has two donor atoms, but only one of them has the capacity to form a co-ordinate bond [or a sigma`(sigma)` bond]
    C
    has two donor atoms, but either of two can form a co-ordinate bond
    D
    forms chelate rings
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