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Amine have higher B.P than correspon...

Amine have higher B.P than corresponding alkane or ethers due to .

A

intermolecular hydrogen bonding

B

intramolecular hydrogen bonding

C

higher polar nature of C-N bond

D

Lone pair of electron on nitrogen atom

Text Solution

Verified by Experts

The correct Answer is:
A

Primary and secondary amine have intermolecular hydrogen bonding because of presence of hydrogen atoms attached to nitrogen.
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Knowledge Check

  • Aniline have higher B.P than correspending alkane or ethers due to

    A
    Resonace stabilization of benzene ring
    B
    resonance stabilization of anilium ion
    C
    more hydrophobic nature of `C_(6)H_(5)` group than `C_(2)H_(5)`group
    D
    more hydrophobic nature `C_(6)H_(5)` group than `C_(2)H_(5)` group
  • Corresponding to alkanes ethers are their

    A
    Alkyl derivative
    B
    Dialkyl derivative
    C
    Alkoxy derivative
    D
    Trialkyl derivative
  • Amines have lower B.P than

    A
    ethers
    B
    alkanes
    C
    alcholes
    D
    alkyl halide
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    Assertion: Boiling and melting point of amides are higher than corresponding acids Reason : It is due to strong intermolecular hydrogen bonding in their molention.

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