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Which of the following cations is most s...

Which of the following cations is most stable?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which of the given cations is the most stable, we will analyze the stability of each cation based on the number of alpha hydrogens and the structural features of the cations. ### Step-by-Step Solution: 1. **Identify the Cations**: - First, we need to identify the structures of the cations provided in the question. This involves looking at the molecular structures to determine where the positive charge is located. 2. **Count Alpha Hydrogens**: - Alpha hydrogens are the hydrogens attached to the carbon atoms adjacent to the positively charged carbon (the alpha carbon). - For each cation, count the number of alpha hydrogens: - **Cation A**: 2 alpha hydrogens - **Cation B**: 1 alpha hydrogen - **Cation C**: 1 alpha hydrogen - **Cation D**: 3 alpha hydrogens 3. **Assess Stability Based on Alpha Hydrogens**: - Generally, the more alpha hydrogens present, the more stable the cation. This is because alpha hydrogens can help stabilize the positive charge through hyperconjugation and inductive effects. - From our counts, Cation D has the most alpha hydrogens (3), followed by Cation A (2), and Cations B and C (1 each). 4. **Consider Structural Factors**: - Next, we need to consider if there are any structural factors that might affect stability. - It is noted that cations formed at bridgehead positions in cyclic compounds are less stable compared to those formed at other positions. 5. **Evaluate Each Cation's Environment**: - If any of the cations are formed at a bridgehead position, they will be less stable. - Cation D, while having the most alpha hydrogens, must also be checked for its position. If it is not at a bridgehead, it will be more stable than those that are. 6. **Conclusion**: - After evaluating both the number of alpha hydrogens and the structural position of the cations, we conclude that Cation D is the most stable due to having the highest number of alpha hydrogens and being in a favorable position. ### Final Answer: The most stable cation among the options is **Cation D**.

To determine which of the given cations is the most stable, we will analyze the stability of each cation based on the number of alpha hydrogens and the structural features of the cations. ### Step-by-Step Solution: 1. **Identify the Cations**: - First, we need to identify the structures of the cations provided in the question. This involves looking at the molecular structures to determine where the positive charge is located. 2. **Count Alpha Hydrogens**: ...
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Knowledge Check

  • Which of the following ions is most stable?

    A
    `CH_(3)CH_(2)overset(+)CH_(2)`
    B
    `CH_(3)overset(+)CHCH_(2)CH_(3)`
    C
    `(CH_(3))_(3)overset(+)C`
    D
    `(CH_(3))_(3)Coverset(+)CH_(2)`
  • Which of the following alkenes is most stable?

    A
    `(CH_(3))_(2)CH=CH_(2)`
    B
    `CH_(3)CH=CHCH_(3)`
    C
    `(CH_(3))_(2)C=C(CH_(3))_(2)`
    D
    `CH_(3)CH=CH_(2)`
  • Which of the following species is most stable?

    A
    `p-O_2N-C_6H_4-overset+CH_2`
    B
    `C_6H_5-overset+CH_2`
    C
    `p-Cl-C_6H_4-overset+CH_2`
    D
    `p-CH_3O -C_6H_4-overset+CH_2`
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