Home
Class 12
CHEMISTRY
For an ideal gas, the isothermal free ex...

For an ideal gas, the isothermal free expansion and adiabatic free expansion are basically the same processes- explain.

Text Solution

Verified by Experts

According to the first law of thermodynamics, `DeltaU=q+w`. In free expansion of a gas, w=0. again, in an adiabatic process, q=0
Hence, in an adiabatic free expansion of an ideal gas, the change in internal energy `DeltaU=0+0=0`. Also, in an isothermal process, the change in internal energy of an ideal gas is zero. again for free expansion of an ideal gas, w=0. so, in an isothermal free expansion of an ideal gas, `DeltaU=q+w or, 0=q+0 or q=0`. therefore, it can be concluded that both processes are basically the same.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise QUESTION ANSWER ZONE FOR BOARD EXAMINATION (VERY SHORT ANSWER TYPE)|26 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise QUESTION ANSWER ZONE FOR BOARD EXAMINATION (SHORT ANSWER TYPE)|35 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Practice Set 6|15 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise EXERCISE (NUMERICAL PROBLEMS)|37 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    CHHAYA PUBLICATION|Exercise PRACTICE SET 15|15 Videos

Similar Questions

Explore conceptually related problems

During an adiabatic reversible expansion of an ideal gas

For the adiabatic expansion of an ideal gas

Knowledge Check

  • In the isothermal expansion of an ideal gas

    A
    there is no change in the temperature of the gas
    B
    there is no change in the internal energy of the gas
    C
    the work done by the gas is equal to the heat supplied to the gas
    D
    the work done by the gas is equal to the chang in its internal energy
  • For isothermal free expansion of an ideal gas-

    A
    `DeltaU=0`
    B
    `DeltaS lt0`
    C
    `DeltaS gt0`
    D
    `DeltaH gt0`
  • In the thermal expansion of an ideal gas

    A
    there is no change in the temperature of the gas
    B
    there is no change in the internal energy of the gas
    C
    the work done by the gas is equal to the heat supplied to the gas
    D
    the work done by the gas is equal to the change in its internal energy
  • Similar Questions

    Explore conceptually related problems

    What is the source of work done by the gas in the adiabatic expansion?

    Adiabatic process is essentially a very fast process. Explain.

    How will the temperature of an ideal gas change in an adiabatic expansion?

    The temperature of a gas decreases in an adiabatic expansion. Explain.

    Sign of DeltaU in adiabatic expansion of a gas is _____.