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For an ideal gas, the isothermal free ex...

For an ideal gas, the isothermal free expansion and adiabatic free expansion are basically the same processes- explain.

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According to the first law of thermodynamics, `DeltaU=q+w`. In free expansion of a gas, w=0. again, in an adiabatic process, q=0
Hence, in an adiabatic free expansion of an ideal gas, the change in internal energy `DeltaU=0+0=0`. Also, in an isothermal process, the change in internal energy of an ideal gas is zero. again for free expansion of an ideal gas, w=0. so, in an isothermal free expansion of an ideal gas, `DeltaU=q+w or, 0=q+0 or q=0`. therefore, it can be concluded that both processes are basically the same.
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CHHAYA PUBLICATION-CHEMICAL THERMODYNAMICS-WARM UP EXERCISE
  1. Among the following processes identify those in which the change in in...

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  2. A closed system undergoes a process AtoB. If it occurs reversible, the...

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  3. For an ideal gas, the isothermal free expansion and adiabatic free exp...

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  4. For chemical changes, why is the change in enthalpy more useful than t...

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  5. From the equation H=W+PV, explain what H is a state function.

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  6. From the definition of enthalpy show that for n mol of an ideal gas H=...

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  7. Prove that for an ideal gas undergoing an isothermal change, DeltaH=0.

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  8. Under what conditions are (i) DeltaU=q(V)& (ii) DeltaH=q(P) ?

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  9. Why is the heat capacity a path-dependent quantity?

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  10. Heat required to raise the temperatuer of 1 mol of a gas by 1^(@)C is ...

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  11. Why is the molar heat capacity at constant pressure greater than that ...

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  12. c(P)-c(V)=xJ*g^(-1)*K^(-1) and C(P,m)-C(V,m)=Xj*mol^(-1)*K^(-1) for an...

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  13. Why is the sign of DeltaH negative for an exothermic reaction and why ...

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  14. A 0.5 mol sample of H(2)(g) reacts with a 0.5 mol sample of Cl(2)(g) t...

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  15. A 1 mol sample of N(2)(g) reacts with 1 mol of O(2)(g) to form 2 mol o...

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  16. Identify the exothermic and endothermic changes: (i) NO(g)+(1)/(2)O(...

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  17. Write down the thermochemical equations for the following reactions: ...

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  18. H(2)(g)+(1)/(2)O(2)(g)toH(2)O(l),DeltaH=-285.8kJ. What will be the val...

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  19. Show that the difference between the heat of reactionn at constant pre...

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  20. What do you mean by the standard state of a substance? Is 25^(@)C the ...

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