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Depict the bonding in the following comp...

Depict the bonding in the following compounds in terms of atomic orbitals involed and predict all the bond angles:
(1) `CD_(3)CH = CH_(2)`
(2) CH_(3)OCH_(3)`

Text Solution

Verified by Experts

The 3 carbon atoms are `sp^(3) , sp^(2) and sp^(2)` - hybridised respectively. Therefore the bond angles about these carbons are `109.5^(@) , 120^(@) and 120^(@)` respectively corres - ponding to tetrahedral and trigonal planar geom etrise.
(2) The carbon and oxyen atoms are all `sp^(3)` - hybridised. So, the bond angles are nearly `109.5^(@)` corresponding to tetrahedral geometry.
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Knowledge Check

  • Arrange the following compounds in increasing order of their boiling points- (a) (CH_(3))_(2)CH-CH_(2)Br (b) CH_(3)CH_(2)CH_(2)CH_(2)Br (c) (CH_(3))_(3)C-Br .

    A
    (b) lt (a) lt (c)
    B
    (b) lt (a) lt (c)
    C
    (c) lt (a) lt (b)
    D
    (c) lt (b) lt (a)
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