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Which will exhibit optical isomerism-...

Which will exhibit optical isomerism-

A

`HO-underset(H)underset(|)overset(H)overset(|)(C)-CO_(2)H`

B

`H_(3)C-underset(OH)underset(|)overset(H)overset(|)(C)-CO_(2)H`

C

`H_(3)C-underset(H)underset(|)overset(CH_(3))overset(|)(C)-COOH`

D

`H_(3)C-underset(CI)underset(|)overset(CH_(3))overset(|)(C)-CO_(2)H`

Text Solution

Verified by Experts

The correct Answer is:
B

`H_(3)C-overset(H)overset(|)underset(OH)underset(|)(C^**)-COOH`, The central C - atom of the given compound is chiral. Hence, this molecule is not superimposable on its mirror image. Therefore, it will exhibit optical isomerism.
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Knowledge Check

  • Which of the following compounds will exhibit geometrical isomersim-

    A
    2 - phenyl - 1 - butene
    B
    1,1 - diphenyl - 1 - propene
    C
    1 - phenyl - 2 - butene
    D
    3 - phenyl - 1 - butene
  • Which of the following acids do not exhibit optical isomerism-

    A
    malic acid
    B
    `alpha` - amino acids
    C
    lactic acid
    D
    tataric acid
  • Which of the following complex species is not expected to exhibit optical isomerism-

    A
    `[Co(en)_(3)]^(3+)`
    B
    `[Co(en)_(2)Cl_(2)]^(+)`
    C
    `[Co(NH_(3))_(3)Cl_(3)]`
    D
    `[Co(en)(NH_(3))_(2)Cl_(2)]^(+)`
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