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A solution contains Fe^(3+), Fe^(2+) and...

A solution contains `Fe^(3+), Fe^(2+) and I^(-)` ions. This solution was treated with iodine at `35^(@)C`.
`E_(Fe^(3+)|Fe^(2+))^(@)=+0.77V and E_(I_(2)|2I^(-))^(@)=+-.536V`. The favourable redox reaction is -

A

`I_(2)` will be reduced to `I^(-)`

B

there will be bo redox reaction

C

`I^(-)` will be oxidised to `I_(2)`

D

`Fe^(2+)` will be oxidised to `Fe^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C

The standard reduction potential of `Fe^(3+)|Fe^(2+)` system is higher than that of `I_(2)|I^(-)` system. Thus `Fe^(3+)` gets reduced and `I^(-)` gets oxidised.
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