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Class 12
CHEMISTRY
Deduce the molecular shape of BrF(3) on ...

Deduce the molecular shape of `BrF_(3)` on the basis of VSEPR theory.

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Text Solution

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In `BrF_(3)` molecule, the central Br-atom has seven electrons in the valence shell. Three of these will form electron-pair bonds with the three fluorine atoms. Thus there are three bond pairs and two lone pairs of electrons. According to VSEPR theory, these will occupy the corners of a trigonal bipyramid. The two lone pairs will occupy the equatorial positions to minimise lone pair-lone pair and the bond pair-bond pair repulsions. In addition, the axial fluorine atoms will be bent towards the equatorial fluorine in order to minimise the lone pair-lone pair repulsions. Therefore, the shape would be that of a slightly bent 'T'.
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Knowledge Check

  • Molecular shape of SF_4, CF_4 and XeF_4 are

    A
    The same with 2,0 and 1 lone pair of electron respectively
    B
    The same with 1,1 and 1 lone pair of electron respectively
    C
    Different with 0, 1 and 2 lone pair of electron respectively
    D
    Different with 1, 0 and 2 lone pair of electron respectively
  • The geometrical shape of CIO_(3)^(-) ion is -

    A
    trigonal pyramidal
    B
    tetrahedral
    C
    trigonal planar
    D
    trigonal bipyramidal
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