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Why is the third ionisation energy of ma...

Why is the third ionisation energy of manganese exceptionally high ?

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Electronic configuration of `Mn : [Ar]3d^(5)4s^(2)`
Electronic configuration of `Mn^(2+):[Ar]3d^(5)`
Since the `Mn^(2+)` ion has half - filled `(3d^(5))` d - subshell, it is highly stable. Hence, a large amount of energy is required to remove an electron from stable `Mn^(2+)` ion to form less stable `Mn^(3+)` ion.
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Knowledge Check

  • If the 1st ionisation energy of H atom is 13.6 eV then the 2nd ionisation energy of He atom is

    A
    27.2eV
    B
    40.8eV
    C
    54.4eV
    D
    108.8eV
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