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An aromatic compound C(7)H(6)Cl(2)(A) , ...

An aromatic compound `C_(7)H_(6)Cl_(2)(A)` , gives AgCl on boiling with alcoholic `AgNO_(2)` solution and yields `C_(7)H_(7)OCl` on treatment with sodium hydroxide. A on oxidation gives monochlorobezoic acid. The compound A is-

A

B

C

D

Text Solution

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The correct Answer is:
A

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Knowledge Check

  • Compound (A) C_(8)H_(9)Br gives a white precipitate when warmed with alcoholic AgNO_(3) . Oxidation of A gives an acid (B) C_(8)H_(6)O_(4) , which easily forms anhydride on heating. The compound (A) is-

    A
    B
    C
    D
  • Reaction of C_(6)H_(5)CH_(2)Br with aqueous sodium hydroxide follows-

    A
    `S_(N)1` mechanism
    B
    `S_(N)2` mechanism
    C
    any of the above two depending upon the temperature of reaction
    D
    Saytzeff rule
  • A compound (C_(6)H_(12)O_(6)) on reaction with phenyl-hydrazine gives a yellow ppt. and with Na produces a mixture of sorbitol and mannitol. The compound is-

    A
    fructose
    B
    glucose
    C
    mannose
    D
    sucrose
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    An organic compound C_(3)H_(8)O_(3) yields on acetylation with acetic anhydride C_(9)H_(14)O_(6) . How many -OH groups are present in the substance ? What is the possible structure ?

    An organic compound 'A' (C_(4)H_(10)O) is optically active. On mild oxidation, it gives a compound 'B' (C_(4)H_(8)O) but upon vigorous oxidation, it gives another compound 'C' (C_(3)H_(6)O_(2)) . The compound 'C' along with 'D' are also formed from 'B' by reacting with iodine in the presence of alkali. Deduce the structures of 'A', 'B', 'C' and 'D' .

    When an aromatic compound A (C_7H_8) is oxidised by alkaline KMnO_4 solution, an organic acid (B) is produced. When B is heated with sodalime, another organic compound (C ) is obtained .When C is allowed to react with CH_3Cl in the presence of anhydrous AlCl_3 ,the starting compound A is regenerated. Identify A,B and C.

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