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Consider the reactions: (i) (CH3)(2)CH...

Consider the reactions:
(i) `(CH_3)_(2)CH-CH_(2)Broverset(C_(2)H_(5)OH)(rarr)(CH_3)_(2)CH-CH_(2)OC_(2)H_(5)+HBr`
(ii) `(CH_3)_(2)CH-CH_(2)Broverset(C_(2)H_(5)O^(-))(rarr)(CH_3)_(2)CH-CH_(2)OC_(2)H_(5)+Br^(-)`.
Mechanism of reactions (i) and (ii) are respectively-

A

`S_(N)1 and S_(N)2`

B

`S_(N)1 and S_(N)1`

C

`S_(N)2 and S_(N)2`

D

`S_(N)2 and S_(N)1`

Text Solution

Verified by Experts

The correct Answer is:
C

Both the reactions follow `S_(N)2` mechanism. If they follow `S_(N)1` mechanism, then the products obtained in both the case will be `CH_(3)-underset(OC_(2)H_(5))underset(|)(C)H-C_(2)H_(5)`.
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CH_3 CH=CH_2overset(Cl_2+H_2O) rArr A.A is :

Write the IUPAC names of : (i) CH_(3)CH_(2)O-underset(CH_(3))(CH)-CH_(2)-CH_(3) (ii) CH_(3)-CH_(2)-O-CH_(2)-underset(CH_(3))underset(|)(CH)-CH_(2)-CH_(3)

Knowledge Check

  • Consider the reactions: (i) (CH_(3))_(2)CH-CH_(2)Broverset(C_(2)H_(5)OH)to(CH_(3))_(2)CH-CH_(2)OC_(2)Hd_(5)+Br^(-) (ii) (CH_(3))_(2)CH-CH_(2)Broverset(C_(2)H_(5)O^(-))to(CH_(3))_(2)CH-CH-(2)OCH_(2)H_(5)+Br^(-) The mechanism of reactions (i) and (ii) are respectively-

    A
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    B
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  • Which reacgent will you use for the following reaction- CH_(3)CH_(2)CH_(2)CH_(3)rarr CH_(3)CH_(2)CH_(2)CH_(2)Cl+CH_(3)CH_(2)CHClCH_(3) .

    A
    `Cl_(2)//UV` light
    B
    `NaCl+H_(2)SO_(4)`
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    D
    `Cl_(2)` gas in the presence of iron in dark
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