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Ionisation energies three hypothetical e...

Ionisation energies three hypothetical elements are given below (in kJ/mole) :
`{:(,I,II,III),(X,122,340,1890),(Y,99,931,1100),(Z,118,1220,16552):}`
Which of the following is likely to be 2nd group element?

A

X

B

Z

C

Y

D

X and Y

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the hypothetical elements (X, Y, or Z) is likely to be a second group element (alkaline earth metal), we will analyze the given ionization energies (IE) for each element. The general electronic configuration for alkaline earth metals is ns², which means that the first two ionization energies should not be significantly different, but there should be a large jump between the second and third ionization energies. ### Step-by-step Solution: 1. **List the Ionization Energies:** - For Element X: IE1 = 122 kJ/mol, IE2 = 340 kJ/mol, IE3 = 1890 kJ/mol - For Element Y: IE1 = 99 kJ/mol, IE2 = 931 kJ/mol, IE3 = 1100 kJ/mol - For Element Z: IE1 = 118 kJ/mol, IE2 = 1220 kJ/mol, IE3 = 16552 kJ/mol 2. **Analyze the Differences Between Ionization Energies:** - For Element X: - Difference between IE1 and IE2: 340 - 122 = 218 kJ/mol - Difference between IE2 and IE3: 1890 - 340 = 1550 kJ/mol - For Element Y: - Difference between IE1 and IE2: 931 - 99 = 832 kJ/mol - Difference between IE2 and IE3: 1100 - 931 = 169 kJ/mol - For Element Z: - Difference between IE1 and IE2: 1220 - 118 = 1102 kJ/mol - Difference between IE2 and IE3: 16552 - 1220 = 15332 kJ/mol 3. **Identify the Element with a Large Jump in Ionization Energies:** - Element X shows a significant jump from IE2 to IE3 (1550 kJ/mol), indicating that after removing the second electron, the next electron is being removed from a much more stable electron configuration (noble gas configuration). - Element Y does not show a large jump between IE2 and IE3. - Element Z has an extremely large jump from IE2 to IE3 (15332 kJ/mol), but the difference between IE1 and IE2 is also significant, which is not typical for alkaline earth metals. 4. **Conclusion:** - Based on the analysis, Element X is the most likely candidate to be a second group element (alkaline earth metal) because it has a reasonable difference between IE1 and IE2, and a large jump between IE2 and IE3. ### Final Answer: The element likely to be a second group element is **Element X**.
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Knowledge Check

  • Ionisation energies three hypothetical elements are given below (in kJ/mole) : {:(,I,II,III),(X,122,340,1890),(Y,99,931,1100),(Z,118,1220,16552):} Which of the following pairs represents elements could be of the same group?

    A
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    C
    X,Z
    D
    X,Y,Z
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    A
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    B
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    C
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    D
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