Home
Class 11
CHEMISTRY
A white crystalline solid (A) on boiling...

A white crystalline solid (A) on boiling with caustic soda solution gave a gas (B), which when passed through an alkaline solution of potassium mercuric iodide gave brown precipitate. The substance (A) on heating gave a gas (X), which rekindled a glowing splinter but did not give brown fumes with nitric oxide. the gas (B) is:

A

`H_(2)S`

B

`NH_(3)`

C

`HCI`

D

`CO_(2)`

Text Solution

Verified by Experts

The correct Answer is:
B
`underset((A))(NH_(4)^(+)) overset(NaOH)rarr underset((B))(NH_(3)) overset(K_(2)HgI_(4))underset(OH^(-))rarr underset(("Brown ppt"))(Hg(NH_(2))I darr)`
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • SALT ANALYSIS

    GRB PUBLICATION|Exercise G: Ist Group Cations|20 Videos

  • SALT ANALYSIS

    GRB PUBLICATION|Exercise H: IInd Group Cations|49 Videos

  • SALT ANALYSIS

    GRB PUBLICATION|Exercise E.Precipitation/Redox Reacttions|48 Videos

  • S BLOCK ELEMENTS

    GRB PUBLICATION|Exercise SUBJECTIVE TYPE|9 Videos

  • THERMODYNAMICS

    GRB PUBLICATION|Exercise All Questions|704 Videos

Similar Questions

Explore conceptually related problems

A white crystalline solid (A) on boiling with caustic soda solution gave a gas (B) which when passed through an alkaline solution of K_(2) [HgI_(4)] gave a brown precipitate. The substance (A) on heating gave a gas (X) which rekindled a glowing splinter but does not give brown fumes with nitric oxide. The gas (X) is:

Explain why a green solution of potassium manganate turns purple and a brown solid is precipitated when CO_(2) gas is bubbled into the solution.

Knowledge Check

  • A white crystalline solid A on boiling with caustic soda solution gave a colourless gas B which when passed through an alkaline solution of potassium mercurio iodide gave a brown ppt. The substance A on heating gave a gas C which rekindled a glowing splinter but did not give brown fumes on air oxidation. The gas B is

    A
    `H_2 S `
    B
    `NH_3`
    C
    `HCl`
    D
    `CO_2`

  • A white crystalline solid (A) on boiling with caustic soda solution gave a gas (B) which when passed through an alkaline solution of K_(2) [HgI_(4)] gave a brown precipitate. The substance (A) on heating gave a gasa (X) which rekindled a glowing splinter but does not give brown fumes with nitric oxide. The gas (X) is:

    A
    `NH_(3)`
    B
    `O_(2)`
    C
    `O_(3)`
    D
    `N_(2)O`

  • A white crystalline solid A on boiling with caustic soda solution gives a gas B which on passing through an alkaline solution of potassium tetraiodomercurate (II) solution gives a brown ppt. The substance A on heating evolves a neutral gas C which is called laughing gas. The gas B is

    A
    `H_(2)S`
    B
    `NH_(3)`
    C
    `HCl`
    D
    `CO_(2)`

    • Similar Questions

    Explore conceptually related problems

    A white crystalline solid A on boiling with caustic soda solution gives a gas B which on passing through an alkaline solution of potassium tetraiodomercurate (II) solution gives a brown ppt. The substance A on heating evolves a neutral gas C which is called laughing gas. The gas C is

    A white crystalline solid A on boiling with caustic soda solution gives a gas B which on passing through an alkaline solution of potassium tetraiodomercurate (II) solution gives a brown ppt. The substance A on heating evolves a neutral gas C which is called laughing gas. The substance A is

    A white crystalline solid 'A' on boiling with caustic soda solution gives a gas 'B', which on passing through an alkaline solution of ptassium tetraiodomercurate (II) solution gives a brown ppt. the substance 'A' on heating eveolves a neutral gas 'C', which is inert at room temperature and reactive a presence of catalyst and does ont give grown fumes with nitric oxide. Q. The gas 'B' is:

    A white crystalline solid 'A' on boiling with caustic soda solution gives a gas 'B', which on passing through an alkaline solution of ptassium tetraiodomercurate (II) solution gives a brown ppt. the substance 'A' on heating eveolves a neutral gas 'C', which is inert at room temperature and reactive a presence of catalyst and does ont give grown fumes with nitric oxide. Q. The gas 'C' is:

    A white crystalline solid 'A' on boiling with caustic soda solution gives a gas 'B', which on passing through an alkaline solution of ptassium tetraiodomercurate (II) solution gives a brown ppt. the substance 'A' on heating eveolves a neutral gas 'C', which is inert at room temperature and reactive a presence of catalyst and does ont give grown fumes with nitric oxide. Q. The substance 'A' is:

    Home
    Profile