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How many alcohols with molecular formula...

How many alcohols with molecular formula `C_(4)H_(10)O` are chiral in nature ?

A

1

B

2

C

3

D

4

Text Solution

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The correct Answer is:
To determine how many alcohols with the molecular formula C₄H₁₀O are chiral in nature, we will follow these steps: ### Step 1: Identify the possible structural isomers of C₄H₁₀O The molecular formula C₄H₁₀O indicates that we are dealing with alcohols. The possible structural isomers of butanol (C₄H₁₀O) can be derived by varying the position of the hydroxyl (-OH) group and the arrangement of carbon atoms. ### Step 2: List the possible isomers 1. **Butan-1-ol (1-butanol)**: CH₃-CH₂-CH₂-CH₂OH 2. **Butan-2-ol (2-butanol)**: CH₃-CH(OH)-CH₂-CH₃ 3. **Isobutanol (tert-butanol)**: (CH₃)₃COH (also known as 2-methyl-1-propanol) 4. **Butan-3-ol (3-butanol)**: CH₃-CH₂-CH(OH)-CH₃ ### Step 3: Identify chiral centers A chiral carbon is a carbon atom that is bonded to four different groups. We will analyze each isomer to identify if they contain chiral centers. 1. **Butan-1-ol**: The carbon with the -OH group is attached to two hydrogen atoms and two carbon atoms, so it is not chiral. 2. **Butan-2-ol**: The carbon with the -OH group is attached to a methyl group (CH₃), a hydrogen atom (H), an ethyl group (CH₂CH₃), and another carbon (CH). This carbon is chiral. 3. **Isobutanol**: The carbon with the -OH group is attached to three methyl groups and one hydrogen atom, so it is not chiral. 4. **Butan-3-ol**: Similar to butan-2-ol, the carbon with the -OH group is attached to a methyl group (CH₃), a hydrogen atom (H), an ethyl group (CH₂CH₃), and another carbon (CH). This carbon is also chiral. ### Step 4: Count the chiral alcohols From the analysis: - Butan-1-ol: Not chiral - Butan-2-ol: Chiral - Isobutanol: Not chiral - Butan-3-ol: Chiral Thus, there are **two chiral alcohols** with the molecular formula C₄H₁₀O: **butan-2-ol** and **butan-3-ol**. ### Final Answer The number of chiral alcohols with the molecular formula C₄H₁₀O is **2**. ---

To determine how many alcohols with the molecular formula C₄H₁₀O are chiral in nature, we will follow these steps: ### Step 1: Identify the possible structural isomers of C₄H₁₀O The molecular formula C₄H₁₀O indicates that we are dealing with alcohols. The possible structural isomers of butanol (C₄H₁₀O) can be derived by varying the position of the hydroxyl (-OH) group and the arrangement of carbon atoms. ### Step 2: List the possible isomers 1. **Butan-1-ol (1-butanol)**: CH₃-CH₂-CH₂-CH₂OH 2. **Butan-2-ol (2-butanol)**: CH₃-CH(OH)-CH₂-CH₃ ...
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Write all the isomeric alcohols with molecular formula C_(4)H_(10)O and give their IUPAC names.

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Knowledge Check

  • Molecular formula C_(4)H_(10)O represent

    A
    Two primary alcohol
    B
    One secondary alcohol
    C
    One tertiary alcohol
    D
    All of these
  • Molecular formula C_4H_10O exhibits

    A
    chain isomerism
    B
    position isomerism
    C
    metamerism
    D
    all of these
  • How many isomeric alcohols with formula C_(4)H_(10)O are possible ?

    A
    2
    B
    3
    C
    4
    D
    5
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