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Which of the following compounds will re...

Which of the following compounds will react with sodium hydroxide solution in water ?

A

`C_(6)H_(5)OH`

B

`C_(6)H_(5)CH_(2)OH`

C

`(CH_(3))_(3)COH`

D

`C_(2)H_(5)OH`

Text Solution

Verified by Experts

The correct Answer is:
A

Phenol is more acidic in nature because by the loss of one proton, it gives phenoxide ion. This phenoxide ion is resonance stabilised. As phenoxide ion is a stable intermediate so, the tendency to give proton is more in phenol than the others. Phenols being more acidic than alcohols, dissolves in NaOH.

Therefore, option (a) is the correct.
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Knowledge Check

  • Which of the following compounds not react with sodium bisulphite

    A
    Benzaldehyde
    B
    Acetone
    C
    Acetophenone
    D
    Acetaldehyde
  • Which of the following compounds does not react with sodium?

    A
    `CH_(3)CH_(2)OH`
    B
    `CH_(3)COOH`
    C
    `CH_(3)CHOHCH_(3)`
    D
    `CH_(3)OCH_(3)`
  • Which of the following compounds react with sodium bicarbonate ?

    A
    Phenol
    B
    Ethnol
    C
    Acetylene
    D
    Picric acid
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