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Explain why SF(4) is easily hydrolysed, ...

Explain why `SF_(4)` is easily hydrolysed, whereas `SF_(6)` is resistant to hydrolysis ?

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To explain why SF₄ is easily hydrolyzed while SF₆ is resistant to hydrolysis, we can break down the reasoning into several steps: ### Step 1: Understanding the Structure of SF₄ and SF₆ - **SF₄** has a sulfur atom bonded to four fluorine atoms and has one lone pair of electrons. This results in a trigonal bipyramidal geometry with a seesaw shape due to the presence of the lone pair. - **SF₆**, on the other hand, has a sulfur atom bonded to six fluorine atoms, resulting in an octahedral geometry. ### Step 2: Hybridization - In SF₄, the hybridization is sp³d, which allows for the formation of four bond pairs and one lone pair. ...
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Give reasons for the following observations : SF_(6) is kinetically an inert substance. Or SF_(6) is inert towards hydrolysis. Or SF_(6) is much less reactive than SF_(4) . Or SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed.

(a) Account for the following observations : (i) SF_(1) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (ii) Chlorine water is a powerful bleaching agent. (iii) Bi (V) is a stronger oxidising agent than Sb(V) (b) What happens when : (i) White phosphorus is heated with concentrated NaOH solution in an inert atmosphere of CO_(2). (ii) XeF_(6) undergoes partial hydrolysis. (Give the chemical equations involved).

Why is SiCl_(4) readily hydrolysed but C Cl_(4) is resistant to hydrolysis?

Explain the following situations : (i) In the structure of HNO_(3) molecule , the N-O bond (121 pm) is shorter than N-OH bond (140pm). (ii) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (iii) XeF_(2) has a straight linear structure and not a bent angular structure.

Account for the following : (i) NH_(3) is a stronger base than PH_(3) (ii) Sulphur has a greater tendency for catention than oxygen. (iii) Bond dissociation energy of F_(2) is less than that of Cl_(2) . (OR) Explain the following situations : (i) In the structure of HNO_(3) moleucle, the N-O bond (121 pm) is shorter than the N-OH bond (140 pm). (ii) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (iii) XeF_(2) has a straight linear structure and not a bent angular structure.

SF_(6) is not easily hydrolysed whereas SF_(4) can be. Assign reason.

Explain the following situations : SF_4 is easily hydrolysed whereas SF is not easily hydrolysed.

Give reasons for the following observations : Why SF_(4) undergoes hydrolysis but not SF_(6) ? Or SF_(6) is inert towards hydroysis. SF_(6) is much less reactive than SF_(4) . Or (i) SF_(4) is easily hydrolysed whereas SF_(6) is not easily hydrolysed. (ii) Sulpher exhibits greater tendency for calenation than selenium. (iii) Sulpher has a higher tendency for catenation than oxygen.

Explain why : SF_(6) is inert and stable but SF_(4) is reactive.

CCl_(4) is stable towards hydrolysis in water whereas SiCl_(4) is easily hydrolysed by water because