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Alcohol (ROH) does not react with NaBr t...

Alcohol (ROH) does not react with NaBr to form alkyl bromide because

A

NaBr is in soluble in alcohol

B

`Br^(-)` is strong base than `OH^(-)`

C

NaBr is an ionic compound

D

`OH^(-)` is a strong base than `Br^(-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of why alcohol (ROH) does not react with NaBr to form alkyl bromide, we can break it down into the following steps: ### Step 1: Understand the Reactants - We have an alcohol (ROH) and sodium bromide (NaBr). The alcohol contains a hydroxyl group (-OH) which is a poor leaving group in nucleophilic substitution reactions. **Hint:** Consider the nature of the functional groups involved in the reaction. ### Step 2: Identify the Nucleophile - In this reaction, the bromide ion (Br-) from NaBr would act as the nucleophile. For a substitution reaction to occur, the nucleophile must be able to displace the leaving group (in this case, -OH). **Hint:** Recall the role of nucleophiles in substitution reactions. ### Step 3: Compare the Strength of the Leaving Group - The hydroxyl ion (OH-) is a strong base and a poor leaving group compared to Br-. For the nucleophilic substitution to occur, Br- must be a stronger nucleophile than OH- is a leaving group. However, OH- is not a good leaving group because it is a strong base. **Hint:** Think about the stability of the leaving groups and their ability to depart from the molecule. ### Step 4: Conclusion on Reaction Feasibility - Since OH- is a stronger base than Br-, it cannot be easily replaced by Br-. Therefore, the reaction between alcohol and NaBr does not proceed to form alkyl bromide (RBr). **Hint:** Reflect on the concept of leaving group ability and how it affects reaction pathways. ### Step 5: Identify the Correct Option - The correct option states that "OH- is a strong base compared to Br-", which explains why the reaction does not occur. Other options provided in the question do not accurately describe the situation. **Hint:** Review the options carefully to determine which one aligns with the reasoning you've established. ### Final Answer Alcohol (ROH) does not react with NaBr to form alkyl bromide because OH- is a stronger base than Br-, making it a poor leaving group in nucleophilic substitution reactions. Thus, the correct option is that "OH- is a strong base compared to Br-."
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Knowledge Check

  • Alcohols reacts with Grignard reagent to form

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    Alkanes
    B
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  • Alcohols react with Grignard reagent to form

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  • Alcohols react with Grignard reagent to form

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    Alkanes
    B
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    C
    Alkynes
    D
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