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Calculate the diameter of one molecule o...

Calculate the diameter of one molecule of an ideal gas having number density `2xx10^(8) cm^(-3)` and mean free path of the molecule is `10^(-8)` cm.

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To calculate the diameter of one molecule of an ideal gas, we can use the formula for the mean free path (λ): \[ \lambda = \frac{1}{\sqrt{2} \pi d^2 n} \] Where: - \( \lambda \) is the mean free path, - \( d \) is the diameter of the molecule, - \( n \) is the number density of the gas. We can rearrange this formula to solve for the diameter \( d \): \[ d = \sqrt{\frac{1}{\sqrt{2} \pi n \lambda}} \] ### Step 1: Substitute the given values We are given: - Number density \( n = 2 \times 10^8 \, \text{cm}^{-3} \) - Mean free path \( \lambda = 10^{-8} \, \text{cm} \) Substituting these values into the rearranged formula: \[ d = \sqrt{\frac{1}{\sqrt{2} \pi (2 \times 10^8) (10^{-8})}} \] ### Step 2: Calculate the denominator First, we calculate the product in the denominator: \[ \sqrt{2} \approx 1.414 \] \[ \pi \approx 3.14 \] Now, calculate: \[ \sqrt{2} \pi n \lambda = 1.414 \times 3.14 \times (2 \times 10^8) \times (10^{-8}) \] This simplifies to: \[ = 1.414 \times 3.14 \times 2 = 8.88 \quad \text{(since } 10^8 \times 10^{-8} = 1\text{)} \] ### Step 3: Substitute back into the diameter formula Now substituting back into the formula for \( d \): \[ d = \sqrt{\frac{1}{8.88}} \] ### Step 4: Calculate the square root Now we calculate: \[ \frac{1}{8.88} \approx 0.1126 \] Taking the square root: \[ d \approx \sqrt{0.1126} \approx 0.335 \, \text{cm} \] ### Step 5: Final result Thus, the diameter of one molecule of the ideal gas is approximately: \[ d \approx 0.33 \, \text{cm} \]
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Knowledge Check

  • Mean free path of a gas molecule is

    A
    inversely proportional to number of molecules per unit volume
    B
    Inversely proportional to diameter of molecule
    C
    directly proportional to square root of absolute temperature
    D
    directly proportional to molecular mass
  • On increasing number density for a gas in a vessel, mean free path of a gas

    A
    Decreases
    B
    Increases
    C
    Remains same
    D
    Becomes double
  • The average speed of air molecules is 485 "ms"^(-1) . At STP the number density is 2.7xx10^(25)m^(-3) and diameter of the air molecule is 2xx10^(-10) m . The value of mean free path for the air molecule is

    A
    `2.5xx10^(-7)m`
    B
    `2.9xx10^(-7)m`
    C
    `3.5xx10^(-7)m`
    D
    `3.9xx10^(-7)m`
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