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The internal energy of 10 g of nitrogen ...

The internal energy of 10 g of nitrogen at N. T. P. is about

A

2575 J

B

2025 J

C

3721 J

D

4051 J

Text Solution

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The correct Answer is:
To find the internal energy of 10 g of nitrogen gas (N₂) at normal temperature and pressure (NTP), we can use the formula for internal energy \( U \) of an ideal gas: \[ U = \frac{f}{2} n R T \] Where: - \( U \) is the internal energy, - \( f \) is the degrees of freedom, - \( n \) is the number of moles, - \( R \) is the universal gas constant (approximately \( 8.314 \, \text{J/mol·K} \)), - \( T \) is the temperature in Kelvin. ### Step 1: Determine the degrees of freedom \( f \) For a diatomic gas like nitrogen (N₂), the degrees of freedom \( f \) is 5. ### Step 2: Calculate the number of moles \( n \) To find the number of moles, we use the formula: \[ n = \frac{\text{mass}}{\text{molar mass}} \] Given: - Mass of nitrogen = 10 g - Molar mass of nitrogen (N₂) = 28 g/mol (since each nitrogen atom has a mass of approximately 14 g) Calculating the number of moles: \[ n = \frac{10 \, \text{g}}{28 \, \text{g/mol}} \approx 0.357 \, \text{mol} \] ### Step 3: Use the temperature \( T \) At normal temperature and pressure (NTP), the temperature \( T \) is 273 K. ### Step 4: Substitute the values into the internal energy formula Now we can substitute the values into the internal energy formula: \[ U = \frac{5}{2} \cdot n \cdot R \cdot T \] Substituting \( n \approx 0.357 \, \text{mol} \), \( R = 8.314 \, \text{J/mol·K} \), and \( T = 273 \, \text{K} \): \[ U = \frac{5}{2} \cdot 0.357 \cdot 8.314 \cdot 273 \] ### Step 5: Calculate the internal energy Now, we can calculate: \[ U = \frac{5}{2} \cdot 0.357 \cdot 8.314 \cdot 273 \approx 2026.53 \, \text{J} \] Rounding this value gives us approximately: \[ U \approx 2025 \, \text{J} \] ### Final Answer The internal energy of 10 g of nitrogen at NTP is approximately **2025 Joules**. ---
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Knowledge Check

  • The volume of 1.0 g of hydrogen at N.T.P. is

    A
    `1.12 dm^(3)`
    B
    `11.2dm^(3)`
    C
    `22.4 dm^(3)`
    D
    `2.24 dm^(3)`
  • The volume of 1.0 g of hydrogen in litres at N.T.P. is

    A
    `2.24`
    B
    `22.4`
    C
    `1.12`
    D
    `11.2`
  • If atmospheric pressure P=1xx10^(5)N//m^(2)andR=8J//"mole"//""^(@)K , then the kinetic energy per mole of a gas at N.T.P. is

    A
    1638 joule/mole
    B
    819 joule/mole
    C
    3276 joule/mole
    D
    4000 joule/mole
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