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Which of the following involves the redu...

Which of the following involves the reduction of copper:

A

`Cu(s)+(1)/(2)O_(2)(g)rarrCuO(s)`

B

`Cu^(2+)(aq)+2I^(-)(aq)rarr2Cul(aq)`

C

`CuCl_(2)(g)+2F^(-)(aq)rarrCuF_(2)+Cl_(2)(g)`

D

None of the above.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options involves the reduction of copper, we need to analyze each option and identify the changes in the oxidation state of copper. ### Step-by-Step Solution: 1. **Analyze Option 1: Cu + 1/2 O2 → CuO** - In this reaction, copper (Cu) is in its elemental form with an oxidation state of 0. - Oxygen (O2) has an oxidation state of 0, and in CuO, oxygen has an oxidation state of -2. - Copper in CuO has an oxidation state of +2. - Since the oxidation state of copper increases from 0 to +2, this represents an **oxidation** process, not reduction. 2. **Analyze Option 2: Cu²⁺ (aq) + 2I⁻ (aq) → 2CuI (aq)** - Here, copper starts as Cu²⁺ with an oxidation state of +2. - In the product CuI, the oxidation state of copper is +1 (since iodine is -1). - The oxidation state of copper decreases from +2 to +1, indicating that copper is being **reduced**. 3. **Analyze Option 3: Cu²⁺ (aq) + 2Cl⁻ (aq) → CuCl₂ (aq)** - In this reaction, copper starts as Cu²⁺ with an oxidation state of +2. - In CuCl₂, copper remains at +2 since chlorine has an oxidation state of -1. - There is no change in the oxidation state of copper, so this reaction does not involve reduction. 4. **Analyze Option 4: None of the above** - Since we have identified that Option 2 involves the reduction of copper, this option is not correct. ### Conclusion: The correct option that involves the reduction of copper is **Option 2**: Cu²⁺ (aq) + 2I⁻ (aq) → 2CuI (aq).

To determine which of the given options involves the reduction of copper, we need to analyze each option and identify the changes in the oxidation state of copper. ### Step-by-Step Solution: 1. **Analyze Option 1: Cu + 1/2 O2 → CuO** - In this reaction, copper (Cu) is in its elemental form with an oxidation state of 0. - Oxygen (O2) has an oxidation state of 0, and in CuO, oxygen has an oxidation state of -2. - Copper in CuO has an oxidation state of +2. ...
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Knowledge Check

  • Which of the following changes involve reduction ?

    A
    The conversion of ferrous sulphate to ferric sulphate
    B
    The conversion of `H_(2)S` to S
    C
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    D
    The conversion of Zn to `ZnSO_(4)`
  • Which of the following in Mendius reduction ?

    A
    `RNO_(2)+ 6H to `
    B
    `RCN + 4H to `
    C
    `RCH = NOH + 4H to `
    D
    `RNC + 2H_(2) to`
  • Which of the following bleaches by reduction

    A
    `CaOCl_(2(aq))`
    B
    `H_2O(2(aq))`
    C
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    D
    `SO_(2(aq))`
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