Home
Class 12
CHEMISTRY
ClF(3) exists but FCl(3) does not. Why ?...

`ClF_(3)` exists but `FCl_(3)` does not. Why ?

Text Solution

Verified by Experts

Chlorine has vacant 3d-orbitals and an electron can be promoted from 3p filled orbital to 3d orbital. Thus, chlorine can show a cavalency of 3 in its compunds and a molecule of `ClF_(3)` can exist. But fluroine has no vacant 2d orbitals and can exhibit only cavalency of one in its compounds. Thus, a molecule of `FCl_(3)` fails to exist.
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise N.C.E.R.T In-Text Questions|34 Videos
  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise N.C.E.R.T. Exercise|40 Videos
  • THE P-BLOCK ELEMENTS

    DINESH PUBLICATION|Exercise Problem 3|1 Videos
  • THE OXYGEN FAMILY

    DINESH PUBLICATION|Exercise PREPARATORY PACKAGE|14 Videos

Similar Questions

Explore conceptually related problems

CIF_(2) exists but FCl_(3) does not. Why?

Give one reason to explain why ClF_(3) exists but FCl_(3) does not exist?

Give reason to explain why ClF_(3) exists but FCl_(3) does not exist.

Give reason to explain why ClF_3 exists but FCl_3 , does not.

Give reason to explain why CIF_(3) exists but FCl_(3) does not exist.

Assertion (A): ClF _(3) exist but FCl_(3) does not exist. Reason (R): ‘p does not have d-orbitals whereas 'Cl' has d-orbitals.

Why PCl_(5) exists but NCl_(5) does not ?

IF_(7) exists but BrF_(7) does not, why ?

BCl_(3) exists but BH_(3) does not. Explain.

OsO_(4) exists but OsF_(8) does not exist. Why?