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Xenon does not form fluorides such as Xe...

Xenon does not form fluorides such as `XeF_(3)` and `XeF_(5)`. Explain.

Text Solution

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We know that all the occupied orbitals in xenon atom are paired. By the promotion of one, two or three electrons from the filled `p-`orbitals to the vacant `d-`orbitals in the valence shell, two, four or six half filled orbitals are formed. Thus, xenon can combine only with even number of fluorine atoms and not odd. In other words, it cannot form compounds like `XeF_(3)` and `XeF_(5)`.
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Give reasons : (i)Xenon does not form fluorides such as XeF_(3) and XeF_(5) .(ii)Out of noble gases, only xenon is known to form established chemicals compounds.

Give reasons : (i) Xenon does not form fluorides such as XeF_(3) and XeF_(5) . (ii) Out of noble gases, only xenon is known to form established chemical compounds.

Knowledge Check

  • Xenon tetrafluoride, XeF_(4) is:

    A
    tetrahedral annd acts as a fluoride donor with `SbF_(5)`
    B
    square planar and acts as a fluoride donor with `PF_(5)`
    C
    square planar and acts as fluoride donor with `NaF`
    D
    see-saw shape and acts as a fluoride donor with `AsF_(5)`
  • In xenon fluorides most reactive in XeF_(6) , XeF_(4) and XeF_(2) is

    A
    `XeF_(6)`
    B
    `XeF_(2)`
    C
    `XeF_(4)`
    D
    All are equally reactive
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