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Among transition metals, the highest oxi...

Among transition metals, the highest oxidation state is exhibited in oxoanions of a metal. Explain.

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The oxoanions of metals have covalent nature in which oxygen is involved in the multiple bonding with the metal atom. This is responsible for the high oxidation state of the metal in oxoanions. Fore example, the element Mn exhibits +7 oxidation state in permanganate ion `(MnO_(4))^(-)`.
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(a) In the titration of FeSO_(4) with KMnO_(4) in the acidic medium, why is dil. H_(2)SO_(4) used instead of dil. HCI ? (b) Give reasons : (i) Among transition metals, the highest oxidation state is exhibited in oxoanions of a metal. (ii) Ce^(4+) is used as an oxidising agent in volumetric analysis. (iii) Transition metals form a number of interstitial compounds. (iv) Zn^(2+) salts are white while Cu^(2+) salts are blue.

Give examples and suggest reason for the following features of the transition metals Chemistry. (ii). A transition metal exhibits highest oxidation state in oxides and fluorides. (iii). The highest oxidation state is exhibited in oxoanions of a metal.

Knowledge Check

  • Which transition metal shows the highest oxidation state ?

    A
    Sc
    B
    Ti
    C
    Mn
    D
    Zn
  • Which transition metal can show highest oxidation state ?

    A
    Sc
    B
    Ti
    C
    Os
    D
    Zn
  • Which transition metal can show highest oxidation state ?

    A
    Sc
    B
    Ti
    C
    Os
    D
    Zn
  • Similar Questions

    Explore conceptually related problems

    Give examples and suggest reasons for the following features of the transition metal chemistry : (i) The lowest oxide of transition metal is basic, the highest is amphoteric acidic. (ii) A transition metal exhibits highest oxidation state in oxides and fluorides. (iii) The highest oxidation state is exhibited in oxoanions of a metal.

    Give example and suggest reasons for the following features of the transition metal chemistry. (a) The lowest oxide of transition metal is basic, the highest is acidic. (b) A transition metal exhibits higher oxidation states in oxides and fluorides. (c) The highest oxidation state is exhibited in oxoanions of a metal.

    (i) Which transition element in 3d series has positive E_(M^(2+//)M)^(@) value and why ? (ii) Name a member of lanthanoid series which is well known to exhibit to exhibit +4 oxidation state and why? (b) Account for the following : (i) The highest oxidation state is exhibited in oxoanions of transition metals. (ii) HCl is not used to acidify KMnO_(4) solution. (iii) Transition metals have high enthalpy of atomisation.

    The highest oxidation state exhibited by a transition metal is

    Transition metal usually exhibit highest oxidation states in their