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3d^4 configuration may have the exchange...

`3d^4` configuration may have the exchange of s

A

four electrons

B

three electrons

C

sixteen electrons

D

six electrons

Text Solution

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The correct Answer is:
To solve the question regarding the `3d^4` electron configuration and the maximum number of exchanges of electrons, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Electron Configuration**: The configuration `3d^4` indicates that there are 4 electrons in the 3d subshell. The d subshell has 5 orbitals. 2. **Determine the Number of Orbitals**: The d subshell has 5 orbitals (dxy, dyz, dzx, dx2-y2, dz2). Each orbital can hold a maximum of 2 electrons, giving a total capacity of 10 electrons. 3. **Understanding Electron Exchange**: Electron exchange refers to the swapping of positions between electrons in the same subshell. We need to calculate how many unique exchanges can occur among the 4 electrons in the 3d subshell. 4. **Counting Possible Exchanges**: - For the **1st electron** (let's label it as E1), it can exchange with 3 other electrons (E2, E3, E4). So, there are 3 possible exchanges. - For the **2nd electron** (E2), it can exchange with 2 remaining electrons (E3, E4) since E1 has already been counted. Thus, there are 2 possible exchanges. - For the **3rd electron** (E3), it can only exchange with the last electron (E4) which has not been counted yet. So, there is 1 possible exchange. - The **4th electron** (E4) cannot exchange with any other since all possible exchanges have been counted. 5. **Total Exchanges Calculation**: To find the total number of unique exchanges, we add the possible exchanges: \[ 3 \text{ (for E1)} + 2 \text{ (for E2)} + 1 \text{ (for E3)} = 6 \] 6. **Conclusion**: The maximum number of exchanges that can occur among the 4 electrons in the `3d^4` configuration is 6. ### Final Answer: The maximum number of exchanges for the `3d^4` configuration is **6**. ---
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Knowledge Check

  • Which of the following electronic configuration have the highest exchange energy :-

    A
    B
    C
    D
  • Value of CFSE, in tetrahedral complex having 3d^4 configuration of metal lon, surrounded by weak field ligands. will be

    A
    `-2/5 triangle_(t)`
    B
    `+2/5 triangle_(t)`
    C
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    D
    `+3/5 triangle_(t)`
  • Statement-1 : The groundstate configuration of Cr is [Ar] 3d^(5) 4s^(1) Statement-2 : The energy of atom is lesser in 3d^(5)4s^(1) configuration compared to 3d^(4)4s^(2) configuration.

    A
    Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
    B
    Staterment-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
    C
    Statement-1 is true, statement-2 is false.
    D
    Statement-1 is false, statement-2 is true.
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    The electronic configuration of valence shell of Cu is 3d^(10)4s^(2) . How is this configuration explained ?

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