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Intermediate product of hydrolysis of cy...

Intermediate product of hydrolysis of cyanide is

A

`RCOONH_4`

B

`RCONH_2`

C

`R-underset(OH)underset(|)C=NH`

D

`R-C-=overset(o+)NH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the intermediate product of hydrolysis of cyanide, we can analyze the process step by step. ### Step-by-Step Solution: 1. **Understanding Cyanide Hydrolysis**: - Cyanides (R-C≡N) can undergo hydrolysis in both acidic and basic conditions to form different products. The hydrolysis process involves the addition of water (H₂O) to the cyanide. 2. **Hydrolysis in Basic Medium**: - In a basic medium, hydroxide ions (OH⁻) attack the carbon atom of the cyanide (R-C≡N). - This results in the formation of an intermediate product, which is an amide (R-C(=O)-NH₂). 3. **Formation of Amide**: - The reaction proceeds with the formation of an amide as the intermediate product. The reaction can be summarized as: - R-C≡N + OH⁻ → R-C(=O)-NH₂ (amide) 4. **Further Hydrolysis**: - The amide can further react with hydroxide ions to eventually form a carboxylic acid (R-COOH). However, the question specifically asks for the intermediate product, which is the amide. 5. **Hydrolysis in Acidic Medium**: - In acidic conditions, the nitrogen of the cyanide is protonated (R-C≡NH⁺), and then water attacks to form an amide (R-C(=O)-NH₂) as well. - The steps are similar to those in the basic medium, leading to the same intermediate product. 6. **Conclusion**: - In both acidic and basic hydrolysis of cyanide, the intermediate product formed is an amide (R-C(=O)-NH₂). Therefore, the correct answer is that the intermediate product of hydrolysis of cyanide is an amide. ### Final Answer: The intermediate product of hydrolysis of cyanide is **R-C(=O)-NH₂ (amide)**.
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Knowledge Check

  • Final product of hydrolysed alkyl cyanide is

    A
    `RCOOH`
    B
    `RCONH_(2)`
    C
    `R - underset(OH)underset(|)(C) = NH`
    D
    `R - C -= overset(oplus)(N)H`
  • Final product of. hydrolysed alkyl cyanide is

    A
    R COOH
    B
    R `CONH_2`
    C
    `R-undersetunderset(OH)|C=NH`
    D
    `R-C-=overset(o+)NH`
  • The product of acid hydrolysis of is

    A
    `HOCH_2CH_2CH_2CH_2CHO+CH_3CHO`
    B
    `HOCH_2CH_2CH_2CH_2CH_2OH+CH_3CHO`
    C
    `HOCH_2CH_2CH_2CH_2CHO+C_2H_5OH`
    D
    `HOCH_2CH_2CH_2CH_2CH_2OH+C_2H_5OH`
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