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The packing fractionin fcc and hcp struc...

The packing fractionin fcc and hcp structure is same. Moreover, this is the highest packing fraction of all the possible unit cells with same atoms. Can you explain this ?

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The arrangement of atoms in hcp is of ABABAB … type and in case of fcc is of ABCABCABC … type. Both in hcp and fcc, the layers are formed of same atoms in similar arrangements but the only difference is the placement of layers on top of each other. Hence, both have same packing fraction. In both the arrangements, the number of atom of same size present around the atom is maximum, i.e. 6. So, the packing fraction is highest.
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Knowledge Check

  • The packing fraction of the primitive cubic unit cell is

    A
    `0.283`
    B
    `0.321`
    C
    `0.523`
    D
    `0.685`
  • In hcp structure, the packing fraction is

    A
    0.68
    B
    0.74
    C
    0.5
    D
    0.54
  • The ratio of packing fraction in fcc, bcc, and cubic structure is, respectively,

    A
    `1: 0.92: 0.70`
    B
    `0.70: 0.92: 1`
    C
    `1: 0.70: 0.92`
    D
    `0.92: 0.70: 1`
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    packing OF atoms,hcp unit cell,ccp unit cell

    Calculate the packing fraction for the K unit cell. K crystallizes in a body-centred cubic unit cell.

    Stracture of unit cell is described in the given figure packing fraction of the unit cell is?

    FCC structure possesses the most close packing of atoms in it.

    packing fraction of a unit cell is drfined as the fraction of the total volume of the unit cell occupied by the atom(s). P.E=("Volume of the atoms(s) present in a unit cell")/("Volume of unit cell")=(Zxx(4)/(3)pir^(3))/(a^(3)) and % of empty space = 100- P.F.xx100 where Z= effective number of stoms in s cube . r= radius of a an atoms a = edge lenght of the cube Packing fraction in face centered cubic unit cell is :