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[P] on treatment with Br2//FeBr3 in "CCl...

[P] on treatment with `Br_2//FeBr_3` in `"CCl"_4` produced a single isomer `C_8H_7O_2Br` while heating [P] with sodalime gave toluene The compound [P] is

A

B

C

D

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A compound A (C_8H_8O_2) react with Br_2//FeBr_3 and gives only one kind of product when A react with sodalime gives toulene find A?

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  • A solid organic compound (P). Of formula C_(15)H_(15)OH was found to be insoluble in water , dilute HCL or dilute NaOH in cold . After prolonged heating of P with aqueous NaOH , a liquid R was found to be floating on the surface of alkaline mixture . R did not solidfified on cooling to room tempreture, it was steam distilled and separated. Also acidification of alkaline mixture with HCI caused precipitation of a white solid S(C_(8)H_(8) O_(2)) . Some additional infromation are given below S on treatment with Br_(2)//FrBr_(3)" in " CCI_(4) produced a single isomer C_(8)H_(7)O_(2) Br while heating 'S' with soda lime gave toluene.

    A
    B
    C
    D
  • Xylene on treatment with Br_(2)/FeBr_(3) give only one product. The xylene used was

    A
    o- Xylene
    B
    p- Xylene
    C
    m- Xylene
    D
    Cannot be determined
  • [P] on treatment with H_(2)CrO_(4) in acetone produced [Q]. [Q] compound upon heating give rise to Acetophenone. The compound [P] is:

    A
    B
    C
    D
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    4 A neutral, resolvable organic compound A has molecular formula (C_(8)H_(16)O_(2)) . A on treatment with LiAlH_(4) gives isomeric B and C(C_(4)H_(10)O) of which only B is optically active. B on treatment with acidified dichromate solution gives D (C_(4)H_(8)O) , which on refluxing with dilute NaOH followed by acidification of product gave E (C_(8)H_(14)O) . E on heating with N_(2)H_(4) in alkaline medium affords F(C_(8)H_(16)) which on treatment with B.H/H,O,/HO produced a resolvable G (C_(8)H_(18)O) . G on treatment with acidified dichromate solution produced H (C_(8)H_(16)O) , which on treatment with MCPBA produces A. Compound (H) is

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    Treatment of compound o with KMnO_(4)//H^(+) gave P, which on heating with ammonia gave Q. The compound Q on treatment with Br_(2)//NaOH produced R.On strong heating ,Q gave S, which on furthur treatment with ethyl2-bromopropanate in the presence of KOH followed by acidfication , gave acidificatin , gave a compound T.4 The compound T is