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Electrode potential depends upon...

Electrode potential depends upon

A

Size of electrode

B

Surface area of electrode

C

Temperature

D

Shape of electrode

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### Step-by-Step Solution: 1. **Understanding Electrode Potential**: - Electrode potential is the measure of the tendency of a chemical species to acquire electrons and thereby be reduced. It is represented by the symbol \( E \). 2. **Nernst Equation**: - The Nernst equation describes the relationship between the electrode potential and the concentration of the reactants and products involved in the electrochemical reaction. The equation is given by: \[ E = E^0 - \frac{0.059}{n} \log Q \] - Here, \( E^0 \) is the standard electrode potential, \( n \) is the number of moles of electrons transferred in the reaction, and \( Q \) is the reaction quotient. 3. **Factors Affecting Electrode Potential**: - **Concentration**: The concentration of the reactants and products affects the value of \( Q \), which in turn affects the electrode potential. - **Temperature**: The temperature influences the electrode potential as it appears in the Nernst equation. Generally, as temperature increases, the electrode potential decreases. - **Nature of the Electrode**: Different materials have different intrinsic properties which can affect the electrode potential. - **pH of the Solution**: The pH can affect the concentration of hydrogen ions in solution, which can influence the electrode potential in reactions involving protons. 4. **Intensive Property**: - Electrode potential is classified as an intensive property, meaning it does not depend on the amount of material present (size, mass, surface area, shape). 5. **Conclusion**: - In summary, the electrode potential depends primarily on temperature, concentration of reactants/products, the nature of the electrode material, and the pH of the solution.
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Knowledge Check

  • In solution, the stability of the d-block compounds depends upon electrode potential. The electrode potential depends upon which of the following parameters. (i) Entlhalpy of sublimation (ii) Ionisation enthalpy (iii) Hydration enthalpy

    A
    i,ii only
    B
    i, ii only iii
    C
    i, iii only
    D
    ii,iii only
  • The hydrogen electrode potential depends on

    A
    Nature of metal used as anode
    B
    The `P^(H)` of the solution
    C
    Both nature of the metal used as anode and the `P^(H)` of the solution
    D
    Nature of the metal used as cathode and `P^(H)` of the soltion
  • The electrode whose potential depends upon the concentration of a particular ion present in its surronding solution is called

    A
    reference electrode
    B
    indicator electrode
    C
    hydrogen electrode
    D
    calomel electrode
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