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H(2)O(2) exists in alkaline medium as...

`H_(2)O_(2)` exists in alkaline medium as

A

`HO_(2)^(-)`

B

`H^(+)`

C

`H_(3)O_(2)^(+)`

D

`O^(2-)`

Text Solution

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The correct Answer is:
To determine the form in which hydrogen peroxide (H₂O₂) exists in an alkaline medium, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Alkaline Medium**: - An alkaline medium is characterized by a high concentration of hydroxide ions (OH⁻). This means that the pH of the solution is greater than 7. 2. **Behavior of H₂O₂ in Alkaline Medium**: - In an alkaline medium, H₂O₂ can behave as a base. This is because the presence of hydroxide ions allows H₂O₂ to donate protons (H⁺ ions). 3. **Reaction of H₂O₂ with Hydroxide Ions**: - When H₂O₂ is in an alkaline medium, it can react with hydroxide ions (OH⁻). The hydroxide ions can extract a proton (H⁺) from H₂O₂, leading to the formation of water (H₂O) and a negatively charged peroxide ion (O₂²⁻). 4. **Formation of Peroxide Ion**: - The reaction can be represented as: \[ H₂O₂ + OH⁻ \rightarrow O₂^{2-} + H₂O \] - Here, the H₂O₂ molecule loses a hydrogen ion (H⁺) and forms a peroxide ion (O₂²⁻) along with water. 5. **Conclusion**: - Therefore, in an alkaline medium, H₂O₂ exists primarily as the peroxide ion (O₂²⁻). ### Final Answer: H₂O₂ exists in alkaline medium as the peroxide ion (O₂²⁻). ---
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For a reaction 2H_(2)O_(2) underset("alkaline medium") overset(I^(-)) to 2H_(2)O+O_(2) (i) H_(2)O_(2)+I^(-) to H_(2)O +IO^(-) (slow) (ii) H_(2)O_(2)+IO^(-1) to H_(2)O +I^(-) + O_(2) (fast) (a) Write rate law for the reaction. (b) Write the overall order of reaction. (c) Out of steps (1) and (2), which one is rate determining step?

Which of the following is oxidized by H_(2)O_(2) in the alkaline medium

Knowledge Check

  • Which of the following undergoes reduction with H_(2)O_(2) in an alkaline medium ?

    A
    `Mn^(2+)`
    B
    `HOCl`
    C
    `PbS`
    D
    `Fe^(2+)`
  • H_(2)O_(2) exists as ……….. In alkaline medium.

    A
    `HO_(2)^(-)`
    B
    `HO_(2)^(oplus)`
    C
    `O_(2)^(2-)`
    D
    Both 1 & 3
  • H_(2)O_(2) exists as ……….. In alkaline medium .

    A
    `HO_(2)^(-)`
    B
    `HO_(2)_(2)^(o+)`
    C
    `O_(2)^(2-)`
    D
    Both 1&3
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    Which of the following is oxidized by H_(2)O_(2) in the alkaline medium

    Which one of the following compounds on reaction with Na_(2)O_(2) in alkaline medium gives yellow colour solution?

    Hydrogen peroxide is a powerful oxidising agent. It is an electron acceptor in acidic and alkaline mediums . H_(2)O_(2) + 2H^(+) + 2e^(-) rarr H_(2)O (in acidic medium ) H_(2)O_(2) + 2e^(-) rarr 2OH^(-) (in alkaline medium) It can also act as reducing agent towards powerful oxidising agents . H_(2)O_(2) rarr 2H^(+) + O_(2) + 2e In alkaline medium , however , its reducing nature is more effective . H_(2)O_(2) + 2OH^(-) rarr 2H_(2)O + O_(2) + 2e^(-) In the reaction , H_(2)O_(2) + O_(3) rarr H_(2)O + 2O_(2) , H_(2)O_(2) acts as :

    Hydrogen peroxide is a powerful oxidising agent. It is an electron acceptor in acidic and alkaline mediums . H_(2)O_(2) + 2H^(+) + 2e^(-) rarr H_(2)O (in acidic medium ) H_(2)O_(2) + 2e^(-) rarr 2OH^(-) (in alkaline medium) It can also act as reducing agent towards powerful oxidising agents . H_(2)O_(2) rarr 2H^(+) + O_(2) + 2e In alkaline medium , however , its reducing nature is more effective . H_(2)O_(2) + 2OH^(-) rarr 2H_(2)O + O_(2) + 2e^(-) In which of the following reactions , H_(2)O_(2) acts a reducing agent ?

    Hydrogen peroxide is a powerful oxidising agent. It is an electron acceptor in acidic and alkaline mediums . H_(2)O_(2) + 2H^(+) + 2e^(-) rarr H_(2)O (in acidic medium ) H_(2)O_(2) + 2e^(-) rarr 2OH^(-) (in alkaline medium) It can also act as reducing agent towards powerful oxidising agents . H_(2)O_(2) rarr 2H^(+) + O_(2) + 2e In alkaline medium , however , its reducing nature is more effective . H_(2)O_(2) + 2OH^(-) rarr 2H_(2)O + O_(2) + 2e^(-) In which of the following reactions , H_(2)O_(2) acts as an oxidising agent ?