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Which will form hydrocarbon with Grignar...

Which will form hydrocarbon with Grignard reagent?

A

`CH_(3)CHO`

B

`CH_(3)CH_(2)OH`

C

`CH_(3)COCH_(3)`

D

`CH_(3)COOCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound will form a hydrocarbon with a Grignard reagent, we need to analyze each option provided. A Grignard reagent is typically represented as R-MgX, where R is an organic group, and MgX is a magnesium halide. The R group acts as a nucleophile and can react with electrophiles to form hydrocarbons. ### Step-by-Step Solution: 1. **Understanding Grignard Reagents**: - Grignard reagents are organomagnesium compounds that can react with various electrophiles to form new carbon-carbon bonds. - The general formula is R-MgX, where R is an alkyl or aryl group, and X is a halogen. 2. **Analyzing Option A: CH3COH (Acetaldehyde)**: - When CH3COH reacts with a Grignard reagent (e.g., CH3MgCl), it will form an alcohol (CH3C(OH)H2) rather than a hydrocarbon. - **Conclusion**: This option does not form a hydrocarbon. 3. **Analyzing Option B: CH3CH2OH (Ethanol)**: - Ethanol has an acidic hydrogen that can react with the Grignard reagent. - When CH3CH2OH reacts with CH3MgCl, the Grignard reagent will deprotonate the alcohol, leading to the formation of CH3-CH2- (ethane) and Mg(OH)Cl. - **Conclusion**: This option forms a hydrocarbon (ethane). 4. **Analyzing Option C: CH3COCH3 (Acetone)**: - Acetone will react with a Grignard reagent, but it will lead to the formation of an alcohol (CH3C(OH)(CH3)2) rather than a hydrocarbon. - **Conclusion**: This option does not form a hydrocarbon. 5. **Analyzing Option D: CH3COOCH3 (Methyl Acetate)**: - Methyl acetate will also react with a Grignard reagent. The reaction will lead to the formation of an alcohol (CH3C(OH)(CH3)2) and a byproduct, but not a hydrocarbon. - **Conclusion**: This option does not form a hydrocarbon. ### Final Answer: The correct option that will form a hydrocarbon with a Grignard reagent is **Option B: CH3CH2OH (Ethanol)**.

To determine which compound will form a hydrocarbon with a Grignard reagent, we need to analyze each option provided. A Grignard reagent is typically represented as R-MgX, where R is an organic group, and MgX is a magnesium halide. The R group acts as a nucleophile and can react with electrophiles to form hydrocarbons. ### Step-by-Step Solution: 1. **Understanding Grignard Reagents**: - Grignard reagents are organomagnesium compounds that can react with various electrophiles to form new carbon-carbon bonds. - The general formula is R-MgX, where R is an alkyl or aryl group, and X is a halogen. ...
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Knowledge Check

  • Which of the following compounds will form hydrocarbon on reaction with Grignard reagent ?

    A
    `CH_(3)CH_(2)OH`
    B
    `CH_(3)CHO`
    C
    `CH_(3)COCH_(3)`
    D
    `CH_(3)CO_(2)CH_(3)`
  • Which of the following compounds will form a hydrocarbon on reaction with a Grignar reagent ?

    A
    `CH_(3)CH_(2)OH`
    B
    `CH_(3)CHO`
    C
    `CH_(3)COCH_(3)`
    D
    `CH_(3)CO_(2)CH_(3)`
  • Grignard reagent adds to

    A
    `gtC=O`
    B
    `gtC-=N`
    C
    `gtC=S`
    D
    All of these
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