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For the reaction: A + B to product (dx)/...

For the reaction: `A + B to` product `(dx)/(dt) = k[A]^(a)[B]^(b)`
if `(dx)/(dt) =k`, then the order of the reaction is:

A

4

B

3

C

1

D

0

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction given the rate equation and the condition that \(\frac{dx}{dt} = k\), we can follow these steps: ### Step 1: Understand the Rate Law Expression The rate of the reaction is given by the expression: \[ \frac{dx}{dt} = k[A]^a[B]^b \] where \(k\) is the rate constant, \([A]\) is the concentration of reactant A, \([B]\) is the concentration of reactant B, and \(a\) and \(b\) are the orders with respect to A and B, respectively. ### Step 2: Analyze the Given Condition We are given that: \[ \frac{dx}{dt} = k \] This implies that the rate of the reaction is equal to the rate constant \(k\). ### Step 3: Set Up the Equation From the rate law expression, if \(\frac{dx}{dt} = k\), we can equate: \[ k[A]^a[B]^b = k \] ### Step 4: Simplify the Equation Dividing both sides by \(k\) (assuming \(k \neq 0\)): \[ [A]^a[B]^b = 1 \] ### Step 5: Analyze the Implications For the equation \([A]^a[B]^b = 1\) to hold true, the concentrations \([A]\) and \([B]\) must be such that their contributions to the rate do not depend on their actual values. This can only happen if both \(a\) and \(b\) are equal to zero. ### Step 6: Determine the Order of the Reaction The order of the reaction is defined as the sum of the powers of the concentration terms in the rate law: \[ \text{Order} = a + b \] Since we have established that \(a = 0\) and \(b = 0\): \[ \text{Order} = 0 + 0 = 0 \] ### Conclusion Thus, the order of the reaction is **zero**. ---
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Knowledge Check

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