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The electronegativity for some elements ...

The electronegativity for some elements on pauline scale of different groups and periods are listed below. Plot these values against atomic number. From the pattern, explain the variation along a period and a group.
`2^nd` group elements : Be (1.6), Mg (1.2). Ca (1.0), Sr (1.0) Ba(0.9)
`17^(th)` group elements : F (4.0), CI (3.0), Br (2.8). I (2.5)
`3^rd` Period elements : Na(0.9), Mg(1.2), AI (1.5), Si(1.8), P(2.1), S(2.5), CI(3.0)
`4^th` period elements : K(0.8), Ca(1.0). Sc(1.3), Ti(1.5), V(1.6), Cr(16), Mn(1.5), Fe(1.8). Co(1.9), Ni(1.9). Cu(1.9). Zn(16), Ga(16), Ge(1.8), As(2.0), Se(2.4), Br(2.8) 

Text Solution

Verified by Experts

`2^nd` group elements :

`17^th` group elements :

As we go down the group, the electronegativity value decreases. Moving down the group, the electronegativity decreases due to the longer distance between the nucleus and the valence electron shell thereby decreasing the attraction, making the atom have less attraction for electrons or protons.
`3^rd` period:

`4^th` period:

The positively charged protons in the nucleus attract the negatively charged electrons. As the number of protons in the nucleus increases, the electronegativity or attraction will increase. Therefore electronegativity increases from left to right across the period. This occurs due to the greater charge on the nucleus, causing the electron bonding pairs to be very attracted to atoms placed further right on the periodic table.
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Covalent radii (in A) for some elements of different groups and periods are listed below. Plot these values against atomic number. From the plot, explain the variation along a period and a group. 2^nd group elements : Be (0.89), Mg (1.36), Ca (1.74), Sr (1.91) Ba(1.98) 17^th group elements : F (0.72), CI (0.99), Br(1.14). T (1.33) 3^rd Period elements : Na(1.57), Mg(1.36). AI (1.25), Si(1.17). P(1.10), S(1.04). C1(0.99) 4^th period elements : K(2.03), Ca(1.74). Sc(1.44). Ti(1.32), V(1.22), Cr(1.17), Mn(1.17) Fe(1.17). Co(1.16). Ni(1.15). Cu(1.17). Zn(1.25), Ga(1.25). Ge(1.22). As(1.21). Se(1.14). Br(1.14)

Explain about the period variation of electronegativity along a group.

Knowledge Check

  • The radioactive element of group 1 is __________

    A
    rubidium
    B
    cesium
    C
    francium
    D
    radium
  • An element belongs to group 15 and 3^("rd") period of the periodic table, its electronic configuration .

    A
    `1s^(2)2s^(2)2p^(4)`
    B
    `1s^(2)2s^(2)2p^(3)`
    C
    `1s^(2)2s^(2)2p^(6)3s^(2)3p^(2)`
    D
    `1s^(2)2s^(2)2p^(6)3s^(2)3p^(3)`
  • An element belongs to group 15 and 3rd period of the periodic table, its electronic configuration would be:

    A
    `1s^(2) 2s^(2) 2p^(4)`
    B
    `1s^(2) 2s^(2) 2p^(3)`
    C
    `1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(2)`
    D
    `1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(2)`
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