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What type of isomers are the following :...

What type of isomers are the following :
`(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]`
`(ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)]`
`(iii) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)]NO_(3)`
`(iv) [Co(H_(2)O)_(2)Cl_(2)(py)_(2)]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
(i) Linkage (ii) Coordination (iii) ionisation (iv) Hydrate
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Similar Questions

Explore conceptually related problems

What type of isomers are the following (a) [Mn(CO)_(5)(SCN)] and [Mn(CO)_(5)(NCS)] (b) [Co(en)-(3)][Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)] ( c) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)] NO_(3) (d) [Co(py)_(2)(H_(2)O)_(2)CI_(2)]CI and [Co(py)_(2)(H_(2)O)CI_(3)]H_(2)O (II) (a) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2))][Cr(NH_(3))_(2)(CN)_(4)] (b) [Pt(NH_(3))_(4)Br_(2)]CI_(2) and [Pt(NH_(3))_(4)CI_(2)]Br_(2) .

(a) Two, cis- and trans (b) Two, cis- and trans (c) No isomerism is exhibited. Illustration 21. What type of isomers are the following [(CO)_(5)MnSCN] and [(CO)_(5) MONCS . (ii) (Co(NH_(3))_(5))3][Cr(CN_(6))] and [Cr(en)_(3)][CO(CN)_(6)] (iii) [CO(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3)) SO_(4)]NO_(3) (iv) [Co(py)_(2)(H_(2)O_(2))Cl_(2)]C l and [Co(py)_(2)(H_(2O))CI_(3)]_(2)O

Knowledge Check

  • What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

    A
    (i) Ionisation (ii) Hydrate
    B
    (i) Linkage (ii) Hydrate
    C
    (i) Ionisation (ii) Linkage
    D
    (i) Linkage (ii) Coordination

  • [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2) are related to each other as :

    A
    geometrical isomers
    B
    linkage isomers
    C
    coordination isomers
    D
    ionisation isomers

  • IUPAC name [Co(NH_(3))_(5)(NO_(2))]Cl_(2) is

    A
    Nitrito-N-pentaammine cobalt (III) chloride
    B
    Nitrito-N-pentaammine cobalt (II) choride
    C
    pentaammine nitrito-N-cobalt (II) chloride
    D
    Pentaamine nitroto-N-cobalt (III) chloride

    • Similar Questions

    Explore conceptually related problems

    (a) Two, cis- and trans (b) Two, cis- and trans (c) No isomerism is exhibited. Illustration 21. What type of isomers are the following [(CO)_(5)MnSCN] and [(CO)_(5) MONCS . (ii) (Co(NH_(3))_(5))3][Cr(CN_(6))] and [Cr(en)_(3)][CO(CN)_(6)] (iii) [CO(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3)) SO_(4)]NO_(3) (iv) [Co(py)_(2)(H_(2)O_(2))Cl_(2)]C l and [Co(py)_(2)(H_(2O))CI_(3)]_(2)O

    Write the type of isomerism exhibited by the following complexes: (i) [Co(NH_(3))_(5)Cl]SO_(4) (ii) [Co(en)_(3)]^(+3) (iii) [Co(NH_(3))_(6)][Cr(CN)_(6)]

    Name the type of isomerism exibited by the following isomers : (1) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)] (2) [Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O (3) [Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2) (4) [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)

    Write the IUPAC name of (i) [Co(NH_(3))_(5)NO_(2)]Cl_(2) (ii) [Cr(H_(2)O)_(5)SCN]^(2+) (iii) [CoCl(NO_(2))(en)_(2)]^(+)

    Write IUPAC names of the following (i) [CoCl_(2)(en)_(2)]SO_(4) (ii) [Ni(CO)_(4)] (iii) K[PtCl_(3)(NH_(3))] (iv) [Cr(en)_(3)]Cl_(3)

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