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What type of isomers are the following :...

What type of isomers are the following :
`(i) [Mn(CO)_(5)SCN] and [Mn(CO)_(5)NCS]`
`(ii) [Co(en)_(3)[Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)]`
`(iii) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)]NO_(3)`
`(iv) [Co(H_(2)O)_(2)Cl_(2)(py)_(2)]Cl and [Co(H_(2)O)Cl_(3)(py)_(2)]H_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
(i) Linkage (ii) Coordination (iii) ionisation (iv) Hydrate
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What type of isomers are the following (a) [Mn(CO)_(5)(SCN)] and [Mn(CO)_(5)(NCS)] (b) [Co(en)-(3)][Cr(CN)_(6)] and [Cr(en)_(3)][Co(CN)_(6)] ( c) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5)SO_(4)] NO_(3) (d) [Co(py)_(2)(H_(2)O)_(2)CI_(2)]CI and [Co(py)_(2)(H_(2)O)CI_(3)]H_(2)O (II) (a) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2))][Cr(NH_(3))_(2)(CN)_(4)] (b) [Pt(NH_(3))_(4)Br_(2)]CI_(2) and [Pt(NH_(3))_(4)CI_(2)]Br_(2) .

What type of isomerism exists in the following pairs of complexes ? (i) [Co(NH_(3))_(5)NO_(3)]SO_(4) and [Co(NH_(3))_(5) SO_(4) ] NO_(3) (ii) [Co(en)(H_(2)O)_(2) Cl_(2)] Cl and [Co(en) (H_(2)O) Cl_(3) ] H_(2)O

[Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2) are related to each other as :

IUPAC name [Co(NH_(3))_(5)(NO_(2))]Cl_(2) is

Name the type of isomerism exibited by the following isomers : (1) [Cr(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(4)(CN)_(2)][Cr(NH_(3))_(2)(CN)_(4)] (2) [Co(py)_(2)(H_(2)O)_(2)Cl_(2)]Cl and [Co(py)_(2)(H_(2)O)Cl_(3)]H_(2)O (3) [Pt(NH_(3))_(4)Br_(2)]Cl_(2) and [Pt(NH_(3))_(4)Cl_(2)]Br_(2) (4) [Co(NH_(3))_(5)NO_(2)]Cl_(2) and [Co(NH_(3))_(5)ONO]Cl_(2)