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Draw the structures of the following met...

Draw the structures of the following metal carbonyls
`(a) [V(CO)_(6)] " " (b) [Cr(CO)_(6)]" " ( c) [Mn_(2)(CO)_(10)]`
`(d) [Fe(CO)_(5)]" " ( e) [Ni(CO_(4)] " " `

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Draw the structures of the following metal carbonyls (a) [Co_(2)(CO)_(8)]" " (b)[Fe_(2)(CO)_(9)]

Calculate the EAN of central atom in the following complexes (a) [Cr(CO)_(6)]" "(b) [Fe(CN)_(6)]^(4-)" " (c ) [Fe(CO)_(5)] " " (d) [Co(NH_(3))_(6)]^(3+) (e ) [Ni(CO)_(4) " " (f) [Cu(CN)_(4)]^(3-)" "(g)[Pd(NH_(3))_(6)]^(4+)" " (h) [PtCl_(6)]^(2-)

Knowledge Check

  • Among the following select the order of decreasing EAN valuse [cr(CO)_(6)] (II) [Cr(CO)_(6)]^(Θ) (III) [Cr(CO)_(6)]^(o+)

    A
    `IgtIIgtIII`
    B
    `IIIgtIIgtI`
    C
    `IIgtIgtIII`
    D
    `II=IgtIII`
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    How many of the following obey's Sidgwick EAN rule ? (a) K_(4)[Fe(CN)_(6)]," "(b) K_(3)[Fe(CN)_(6)] , (c ) Mn_(2)(CO)_(10)," "(d) [Fe(H_(2)O)_(5)NO]SO_(4) , (e ) Na_(2)[Fe(CN)_(5)NO]," "(f) [Co_(2)(CO)_(8)] , (g) [Fe(pi-C_(5)H_(5))_(2)]

    How many of the following obey's Sidgwick EAN rule ? (a) K_(4)[Fe(CN)_(6)]," "(b) K_(3)[Fe(CN)_(6)] , (c ) Mn_(2)(CO)_(10)," "(d) [Fe(H_(2)O)_(5)NO]SO_(4) , (e ) Na_(2)[Fe(CN)_(5)NO]," "(f) [Co_(2)(CO)_(8)] , (g) [Fe(pi-C_(5)H_(5))_(2)]

    Which of the following complex is having highest M-C bond order? (1) [Ni(CO)_(4)] (2) [Fe(CO)_(5)] (3) [V(CO)_(6)]^(-) (4) [Mn(CO)_(6)]^(+)

    Dedue the value of x in the following compounds. (a) [Mo(CO)_(x)] (b) [Co_(2)(Co)_(x)]^(2-) (c ) Hx (Cr (CO)_(5) (d) HxCo(CO)_(4) (e) [Fe (C_(5)H_(5))_(2)] (f) [Cr (C_(6)H_(6))_(2)] .

    How many of the given complexes follow E.A.N rule ? (a) [Fe(CO)_(5)] (b) [Co_(2)(CO)_(8)] ( c) [Fe(C_(5)H_(5))_(2)] (d) K_(3)[Fe(CN)_(6)] ( e) [Fe(NO)_(2)9CO)_(2)] (f) [CoF_(6)]^(4-)

    Find the total no. of unpaired e~ present in the following complexes. (i) [Fe(CO)_(5)] , (ii) [Cr(CO)_(6)] (iii) [Fe(CN)_(6)]^(4-) , (iv) [Mn(CN)_(6)]^(4-)

    Calculate "EAN" of metal atoms in the following Fe(CO)_(5) (b) Co_(2)(CO)_(8) (c ) Fe(NO)_(2)(CO)_(3) (d) Fe(C_(5)H_(5))_(2) .