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Cu^(2+) ions with NH(4)OH solution gives...

`Cu^(2+)` ions with `NH_(4)OH` solution gives

A

Blue ppt.

B

Blue solution

C

Violet ppt.

D

None of these

Text Solution

Verified by Experts

`Cu^(2+) +4NH_(4)OH to underset("Deep blue solution")([Cu(NH_(3))_(4)]^(2+))+4H_(2)O`
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FeSO_4 solution mixed with (NH_4)_2SO_4 solution is 1:1 molar ratio gives the test of Fe^(2+) ion but CuSO_4 solution mixed with aqueous ammonia in 1:4 molar ratio does not give the test of Cu^(2+) ion. Explain why?

Determine the concentration of hydroxyl ions in 0.4 M NH_(4) OH solution having (i) no ammonium chloride (ii) 5.35 g of NH_(4)Cl per litre of the solution . Ionization constnat of NH_(4)OH is 1.8 xx10^(-5)

Knowledge Check

  • An aqueous solution containing NH_(4)Cl,FeCl_(3) and MnCl_(2) is treated with NH_4OH solution. The observation is that:

    A
    both `Fe^(3+)` and `Mn^(2+)` will precipitate as hydroxides
    B
    only will `Fe^(3+)`precipitate as hydroxide
    C
    only `Mn^(2+)` will precipitate as hydroxide
    D
    `NH_(4)Cl` will crystallize out from the solution
  • Calomel reacts with NH_(4)OH to give

    A
    `HgNH_(2)Cl`
    B
    `NH_(2)-Hg-Hg-Cl`
    C
    `Hg_(2)O`
    D
    `HgO`
  • When disodium hydrogenphosphate is added to the a salt solution of Mg^(2+) in the presence of NH_(4)OH , it gives

    A
    A white ppt.
    B
    A pink ppt.
    C
    `Mg(NH_(4))PO_(4)`
    D
    `Mg(NH_(4))HPO_(4)`
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    FeSO_(4) solution mixed with (NH_(4))_(2)SO_(4) solution (in molar ratio 1 : 1) gives the test of Fe^(2+) ion but CuSO_(4) solution mixed with liquid NH_(3) (in the molar ratio 1 : 4 ) does not give the test of Cu^(2+) . Explain why.

    Sodiumfusion Extract is acidified with HNO_(3) and then treated with AgNO_(3) solution if the organic compound contains halogens. In which of halogen gives white precipitate & which is soluble in NH_(4)OH solution. Second halogen gives yellow ppt and which is insoluble in NH_(4)OH solution. Identify the halogens respectively.

    FeSO_(4) solution mixed with (NH_(4))_(2)SO_(4) solution in 1 : 1 molar ratio gives the test of Fe^(2+) ion but CuSO_(4) solution mixed with aqueous ammonia in 1 : 4 molar ratio does not give the test of Cu^(2+) ion. Explain, why ?

    Which will not give precipitate with NH_(4)OH Solution ?

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