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In going from O(2) to O(2)^(+), the bond...

In going from `O_(2)` to `O_(2)^(+)`, the bond dissociation energy increases and bond length decreases. Do we expect the same behaviour for the change `N_(2)` to `N_(2)^(+)`?

Text Solution

AI Generated Solution

To determine whether the behavior observed in the transition from \( O_2 \) to \( O_2^+ \) (where bond dissociation energy increases and bond length decreases) is the same for the transition from \( N_2 \) to \( N_2^+ \), we can follow these steps: ### Step 1: Understand Bond Order Bond order is a measure of the number of chemical bonds between a pair of atoms. It can be calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} \left( \text{Number of electrons in bonding orbitals} - \text{Number of electrons in anti-bonding orbitals} \right) \] ...
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The bond dissociation energy of N_(2)^(+) is less than that of N_(2) . Show why this is the case.

0.Changing N_(2) to N_(2)^(+) ,the dissociation energy of N-N bond.....and on changing O_(2) to O_(2)^(+) the dissociation energy of O-O bond..... (A) increases,decreases (B) decreases,increases (C) decrease in both cases (D) increases in both cases

Knowledge Check

  • In the reaction N_(2)O_(4) hArr 2NO_(2) , the degree of dissociation of N_(2)O_(4) increases with the

    A
    increase in pressure
    B
    Decrease in temperature
    C
    increase in volume
    D
    presence of catalyst
  • When is molecules N_(2), O_(2), F_(2) are arranged in order of increasing bond strength, which order is correct?

    A
    `N_(2),O_(2),F_(2)`
    B
    `N_(2),F_(2),O_(2)`
    C
    `O_(2),N_(2),F_(2)`
    D
    `F_(2),O_(2),N_(2)`
  • At 60^(@) N_(2)O_(4) is 50% dissociated at this temperature and one atmosphere pressure the standard free energy change is

    A
    `-863.8Jmol^(-1)`
    B
    `-963.8Jmol^(-1)`
    C
    `-973.8Jmol^(-1)`
    D
    `-796.9Jmol^(-1)`
  • Similar Questions

    Explore conceptually related problems

    Do N_(2)^(+) and O_(2)^(+) have same bond order?

    Arrange the molecules H_(2), O_(2), F_(2) and N_(2) in order of increasing bond lengths.

    Arrange O _(2) H_(2)O_(2) and O _(3) in the correct order of decreasing O-O bond length.

    Explain why N_(2) has greater bond dissociation energy than N_(2)^(+) whereas O_(2)^(+) has greater bond dissociation energy than O_(2) .

    Explain why N_(2) has a greater bond dissociation energy than N_(2)^(+) while O_(2) has lesser bond dissociation energy than O_(2)^(+).