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Which of the following compound is the m...

Which of the following compound is the most basic?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which compound is the most basic among the given options, we need to analyze the structure of each compound and the factors that influence basicity. ### Step-by-Step Solution: 1. **Understanding Basicity**: Basicity refers to the ability of a compound to donate a lone pair of electrons. The more readily a compound can donate its lone pair, the more basic it is. Factors that influence basicity include electron density and the presence of electron-withdrawing or electron-donating groups. 2. **Analyzing Option A**: - In this compound, the nitrogen atom has a lone pair that can potentially be donated. However, this lone pair is involved in conjugation with a nearby aromatic ring, which decreases its availability for donation. Therefore, the basicity is reduced. 3. **Analyzing Option B**: - Similar to Option A, this compound also has a nitrogen atom with a lone pair. However, it is affected by a nitro group at the meta position. The nitro group is an electron-withdrawing group (due to its -I effect), which decreases the electron density on the nitrogen, making it less basic. 4. **Analyzing Option C**: - This compound has a nitrogen atom that can donate a lone pair, but it is also affected by a nitro group. The nitro group is in a position that allows for resonance (conjugation), which significantly reduces the electron density on the nitrogen. Thus, its basicity is also low. 5. **Analyzing Option D**: - This compound contains a benzene ring with a -CH2-NH2 group. The nitrogen's lone pair is not involved in conjugation with the benzene ring, allowing it to be more available for donation. There are no strong electron-withdrawing groups present, which means the electron density on the nitrogen remains high. Therefore, this compound is expected to be the most basic. 6. **Conclusion**: Based on the analysis, Option D is the most basic compound among the options provided. ### Final Answer: **The most basic compound is Option D.**
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