Home
Class 12
CHEMISTRY
pK(b) of aniline is more than that of me...

`pK_(b)` of aniline is more than that of methylamine. Why?

Text Solution

AI Generated Solution

To understand why the \( pK_b \) of aniline is more than that of methylamine, we need to analyze the basicity of both compounds. Basicity refers to the ability of a compound to accept protons (H⁺ ions), and it is often measured by the base dissociation constant (\( K_b \)). ### Step 1: Understand the Structures of Aniline and Methylamine - **Aniline (C₆H₅NH₂)**: Aniline consists of a benzene ring attached to an amino group (-NH₂). The structure can be represented as: \[ \text{C}_6\text{H}_5\text{NH}_2 \] - **Methylamine (CH₃NH₂)**: Methylamine is a simple amine with a methyl group attached to the amino group. Its structure is: ...
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MODERN PUBLICATION|Exercise REVISION EXERCISES SHORT ANSWER QUESTIONS|49 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MODERN PUBLICATION|Exercise REVISION EXERCISES LONG ANSWER QUESTIONS|5 Videos
  • ORGANIC COMPOUNDS CONTAINING NITROGEN

    MODERN PUBLICATION|Exercise REVISION EXERCISES ASSERTION REASON QUESTIONS|10 Videos
  • HALOALKANES AND HALOARENES

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|11 Videos
  • POLYMERS

    MODERN PUBLICATION|Exercise Competition file (OBJECTIVE TYPE QUESTIONS) (C. MULTIPLE CHOICE QUESTIONS)(Integer Type Questions)|6 Videos

Similar Questions

Explore conceptually related problems

Account for the following: (i) pK_(b) of aniline is more than that of methylamine. (ii) Ethylamine is soluble in water whereas aniline is not. (iii) Methylamine in water reacts with ferric chloride to precipitate hydrated ferric oxide. (iv) Although amino group is o– and p– directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline. (v) Aniline does not undergo Friedel-Crafts reaction. (vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide synthesis is preferred for synthesising primary amines.

Aniline is more basic than

Aniline is less/more basic than ethylamine.

K_(b) of p-methylaniline is more / less than aniline.

MODERN PUBLICATION-ORGANIC COMPOUNDS CONTAINING NITROGEN -REVISION EXERCISES VERY SHORT ANSWER QUESTIONS
  1. What happens when aniline is treated with Br(2) water?

    Text Solution

    |

  2. Give one reaction that can be used as a test for primary amines.

    Text Solution

    |

  3. pK(b) of aniline is more than that of methylamine. Why?

    Text Solution

    |

  4. Convert aniline the phenylisocyanide

    Text Solution

    |

  5. Arrange the following in the increasing order of basicity: aniline, ...

    Text Solution

    |

  6. What is carbylamine test for 1^(@) amines?

    Text Solution

    |

  7. Arrange the following in the increasing order of their basic strength ...

    Text Solution

    |

  8. The strongest. hasc among the following compounds is NH(3), H(3)CNH(...

    Text Solution

    |

  9. Complete the reaction: CH(3)-CH(2)C-=N overset(Na(Hg) // C(2)H(5)OH)...

    Text Solution

    |

  10. What happens when benzene diazonium chloride solution is added slowly ...

    Text Solution

    |

  11. Write the IUPAC name of

    Text Solution

    |

  12. How is benzamide converted into benzylamine?

    Text Solution

    |

  13. Write down diazotisation reaction.

    Text Solution

    |

  14. Complete the following reaction: Ar-NH(2) underset(0-5^(@)C)overset(...

    Text Solution

    |

  15. Write down Hinsberg's test for primary amines.

    Text Solution

    |

  16. Write IUPAC name of the following compound : CH(3)NHCH (CH(3))(2)

    Text Solution

    |

  17. Write IUPAC name of the following compound (CH(3)CH(2))(2) NCH(3)

    Text Solution

    |

  18. Arrange the following in increasing order of base strength in gas phas...

    Text Solution

    |

  19. Arrange the following in decreasing order of solubility in water: (C...

    Text Solution

    |

  20. Arrange the following compounds is increasing order of solubility in w...

    Text Solution

    |