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II. Read the following passage and answe...

II. Read the following passage and answer questions 6-10 that follow :
During organic reactions, a covalent bond between two carbon atoms or carbon atom and some other atom is broken and a new bond is formed. The fission of bonds can be homolytic or heterolytic forming free radicals, carbocations carbanions, carbenes, etc. This also depends upon the displacement, of electron in a bond and is governed by inductive effect, electromeric effect, reasonance and hyperconjugation.
Do `(CH_3)_ 3 C^(+)` and `( CH_3 )_3 C^(-)` have same structure? Explain.

Text Solution

AI Generated Solution

To determine whether `(CH₃)₃C^(+)` (tert-butyl cation) and `(CH₃)₃C^(-)` (tert-butyl anion) have the same structure, we need to analyze their hybridization and molecular geometry. ### Step 1: Identify the hybridization of the carbon in both species. 1. **For `(CH₃)₃C^(+)`**: - The central carbon atom is bonded to three methyl groups (CH₃) and has a positive charge. - The carbon atom has a total of 4 valence electrons (group 14). - With three bonds to the methyl groups and one positive charge, the effective electron count is 3 (from the bonds) + 0 (from the positive charge) = 3. ...
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II. Read the following passage and answer questions 6-10 that follow : During organic reactions, a covalent bond between two carbon atoms or carbon atom and some other atom is broken and a new bond is formed. The fission of bonds can be homolytic or heterolytic forming free radicals, carbocations carbanions, carbenes, etc. This also depends upon the displacement, of electron in a bond and is governed by inductive effect, electromeric effect, reasonance and hyperconjugation. Which of the two CH_2 = CH^(-) or HC -= C^(-) is a better nucleophile?

II. Read the following passage and answer questions 6-10 that follow : During organic reactions, a covalent bond between two carbon atoms or carbon atom and some other atom is broken and a new bond is formed. The fission of bonds can be homolytic or heterolytic forming free radicals, carbocations carbanions, carbenes, etc. This also depends upon the displacement, of electron in a bond and is governed by inductive effect, electromeric effect, reasonance and hyperconjugation. Which of the two Ph_3 C^(+) or (CH_2)_3 C^(+) is more stable and why?

Knowledge Check

  • Ethylene has ………. Bond between two carbon atoms.

    A
    a single
    B
    a double
    C
    a triple
    D
    an ionic
  • The bond between carbon atom (1) and carbon atom (2) in compound

    A
    `sp^(3)` and `sp^(2)` hybridised
    B
    `sp^(2)` and `sp^(3)` hybridised
    C
    sp and `sp^(2)` hybridised
    D
    sp and sp hybridised
  • Carbon forms bonds with other atoms

    A
    by gaining electrons
    B
    by losing electrons.
    C
    by sharing electrons
    D
    none of the above
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    II. Read the following passage and answer questions 6-10 that follow : During organic reactions, a covalent bond between two carbon atoms or carbon atom and some other atom is broken and a new bond is formed. The fission of bonds can be homolytic or heterolytic forming free radicals, carbocations carbanions, carbenes, etc. This also depends upon the displacement, of electron in a bond and is governed by inductive effect, electromeric effect, reasonance and hyperconjugation. Which of the following is most stable and why? CH_(3)^(-) , overset(-) CH_2 CI, overset(-) CH CI_2, ""^(-) CCI_3

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