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Hexane has four structural isomers....

Hexane has four structural isomers.

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False : Hexane has 5 structural isomers. These are :
(i) n-hexane,
(ii) 2-methylpentane,
(iii) 3-methylpentane,
(iv) 2,2-dimethylbutane,
(v) 2,3-dimethylbutane
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