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The colour of KMnO(4) solution is decol...

The colour of `KMnO_(4)` solution is decolourised by `Fe^(+2)` solution, one mole of `Fe^(2+)` reacts with x moles of `KMnO_(4)` Find x.

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To solve the problem, we need to determine how many moles of potassium permanganate (KMnO₄) react with one mole of ferrous ion (Fe²⁺) in an acidic medium. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction between KMnO₄ and Fe²⁺ in an acidic medium can be represented as: \[ \text{MnO}_4^- + \text{Fe}^{2+} \rightarrow \text{Mn}^{2+} + \text{Fe}^{3+} \] 2. **Determine Oxidation States**: - In KMnO₄, manganese (Mn) is in the +7 oxidation state. - In the product, Mn²⁺, manganese is in the +2 oxidation state. - For Fe²⁺, it is oxidized to Fe³⁺, changing from +2 to +3. 3. **Calculate Change in Oxidation States**: - For Mn: The change in oxidation state is \( +7 \) to \( +2 \), which is a change of \( 5 \) (7 - 2 = 5). - For Fe: The change in oxidation state is \( +2 \) to \( +3 \), which is a change of \( 1 \) (3 - 2 = 1). 4. **Determine the n-factor**: - The n-factor for Fe²⁺ is \( 1 \) (since it changes by 1). - The n-factor for MnO₄⁻ is \( 5 \) (since it changes by 5). 5. **Set Up the Equivalent Equation**: According to the concept of equivalents: \[ \text{Equivalents of Fe}^{2+} = \text{Equivalents of KMnO}_4 \] This can be expressed as: \[ 1 \text{ mole of Fe}^{2+} \times 1 \text{ (n-factor of Fe)} = x \text{ moles of KMnO}_4 \times 5 \text{ (n-factor of KMnO}_4) \] 6. **Solve for x**: \[ 1 = 5x \] \[ x = \frac{1}{5} = 0.2 \] ### Final Answer: Thus, one mole of Fe²⁺ reacts with **0.2 moles of KMnO₄**.

To solve the problem, we need to determine how many moles of potassium permanganate (KMnO₄) react with one mole of ferrous ion (Fe²⁺) in an acidic medium. ### Step-by-Step Solution: 1. **Identify the Reaction**: The reaction between KMnO₄ and Fe²⁺ in an acidic medium can be represented as: \[ \text{MnO}_4^- + \text{Fe}^{2+} \rightarrow \text{Mn}^{2+} + \text{Fe}^{3+} ...
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Moist SO_(2) decolourises KMnO_(4) solution .

Which do not decolourise KMnO_(4) in aqueous solution?

Knowledge Check

  • The colour of KMnO_(4)//H^(o+) will be decolourised by:

    A
    `S^(2-)` solution
    B
    `SO_(3)^(2-)` solution
    C
    both (a) and (b)
    D
    none of these
  • How many mole of FeSO_(4) reacted with one mole of KMnO_(4) in acidic medium?

    A
    `2/5`
    B
    5
    C
    `1/2`
    D
    `1/5`
  • One mole of acidic KMnO_(4) reacts with :

    A
    `(5)/(3) " mol of " FeC_(2)O_(4)`
    B
    `(5)/(2) " mol of " SO_(2)`
    C
    4 mol of FeS
    D
    1 mol of `H_(2)SO_(4)`
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