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Derive the integrated rate equation for rate constant of Zero order reaction.

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Consider a zero reaction `R rarr P`
Rate `= K[R]^(0)`
Rate `= K xx 1` where K = rate
constant (or) velocity constant.
Rate `= (-d[R])/(dt)`
`(-d[R])/(dt) = K rArr d[R] = -K dt`
`int d[R] = -K. int d t`
`[R] = -Kt + 1`
I = integration constant
To find I, when t = 0, `[R] = [R_(0)]`
`[R_(0)] = -k xx 0 + 1`
`I = [R_(0)]`
Substituting in eq. (1)
`[R] = -kt + [R_(0)]`
`K = [R_(0)] - [R]//t`
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OSWAAL PUBLICATION-CHEMICAL KINETICS-Topic - 2 (ORDER OF A REACTION , INTEGRATED RATE EQUATIONS AND HALF LIFE OF A REACTION ) ( Long Answer Type Questions - I)
  1. Derive the integrated rate equation for rate constant of Zero order re...

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  2. Derive an intergrated rate for the first order reaction.

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  3. Thermal decomposition of a compound is of first order. If 50% of the c...

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  4. Rate constant of a first order reaction A products is 0.016 min^(-1). ...

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  5. The following data were obtained during the first order thermal decomp...

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  6. Rate constant k for a first order reactions has been found to be 2.54 ...

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  7. With the help of a diagram, explain the physical significance of energ...

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  8. The rate of a reaction becomes four times when the temperature changes...

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  9. The rate of most reactions becomes double when their temperature is ra...

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  10. Rate constant of reaction at 300 K and 400 K are 0.0345 S^(-1) and 0.1...

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  11. The rate constant of a first order reaction at 300 K and 310 K are res...

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  12. Define energy of activation. Draw a diagram of energy profile to show ...

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  13. Half life of a first order reaction completes in 5 minutes. What perse...

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  14. With graphical representation explain the effect of temperature on the...

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  15. What will be the effect of temperature on rate constant ?

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  16. The decomposition of A into products has a value of k as 4.5 xx 10^(3)...

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  17. In general it is observed that the rate of a chemical reaction doubles...

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