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The complex, [Co(NH(3))(4)Cl(2)]^(+) is ...

The complex, `[Co(NH_(3))_(4)Cl_(2)]^(+)` is known to exist in two different coloured forms. This is due to

A

ionisation isomerism

B

optical isomerism

C

geometrical isomerism

D

linkage isomerism

Text Solution

Verified by Experts

The correct Answer is:
C
`[Ma_(4)b_(2)]^(npm)` formula compounds will exhibit geometrical isomerism, not optical isomerism.
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Consider the following arrangements of the octahedral complex ion [Co(NH_(3))_(4)Cl_(2)]^(+) which of the following statements is incorrect regarding these structure.

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Knowledge Check

  • The complex ion [Cu(NH_(3))_(4)]^(2+) has :

    A
    The tetrahedral configuration & one unpaired electron
    B
    Square planar configuration & one unpaired electron
    C
    Square planar & two unpaired electron
    D
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  • The IUPAC name of [Co(NH_3)_4Cl(NO_2)Cl] is

    A
    Tetraamminechloridonitrito-N-cobalt(III) chloride
    B
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    C
    Tetraamminechloronitrocobalt(I) chloride
    D
    Tetraamminechloronitrocobalt(III) chloride

  • One mole of the complex Co(NH_(3))_(5)Cl_(3) gives 3 moles o f ions on dissolution in water. One mole of he same complex reacts with two moles of AgNO_(3) solution to yield two moles of AgCl(s). The structure of the complex is

    A
    `[Co(NH_(3))_(5)Cl]Cl_(2)`
    B
    `[Co(NH_(3))_(3)Cl_(3)].2NH_(3)`
    C
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    D
    `[Co(NH_(3))_(6)]Cl_(3)`

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