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A molecule possessing dipole moment is...

A molecule possessing dipole moment is

A

`CH_(4)`

B

`H_(2)O`

C

`BF_(3)`

D

`CO_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which molecule possesses a dipole moment, we need to analyze the molecular geometry and electronegativity of the atoms involved in each molecule. Here’s a step-by-step solution: ### Step 1: Analyze CH4 (Methane) - **Structure**: Tetrahedral (C at the center with 4 H atoms) - **Electronegativity**: Carbon (C) is less electronegative than Hydrogen (H). - **Dipole Moment**: The dipole moments from each C-H bond point towards carbon, but they are symmetrically arranged. - **Result**: The dipole moments cancel each other out, resulting in a net dipole moment of zero. **Hint**: Consider the symmetry of the molecule and the direction of dipole moments. ### Step 2: Analyze H2O (Water) - **Structure**: Bent (V-shaped) with O at the center and H atoms at an angle. - **Electronegativity**: Oxygen (O) is more electronegative than Hydrogen (H). - **Dipole Moment**: The dipole moments from each O-H bond point towards oxygen. - **Result**: The dipole moments do not cancel due to the bent shape, resulting in a net dipole moment directed towards oxygen. **Hint**: Look for molecular shapes that prevent dipole cancellation. ### Step 3: Analyze BF3 (Boron Trifluoride) - **Structure**: Trigonal planar (B at the center with 3 F atoms). - **Electronegativity**: Fluorine (F) is more electronegative than Boron (B). - **Dipole Moment**: The dipole moments from each B-F bond point towards fluorine. - **Result**: The dipole moments are symmetrically arranged and cancel each other out, resulting in a net dipole moment of zero. **Hint**: Check if the molecule is symmetrical and how the dipole moments align. ### Step 4: Analyze CO2 (Carbon Dioxide) - **Structure**: Linear (O=C=O). - **Electronegativity**: Oxygen (O) is more electronegative than Carbon (C). - **Dipole Moment**: The dipole moments from each C=O bond point towards oxygen. - **Result**: The dipole moments are equal in magnitude but opposite in direction, resulting in a net dipole moment of zero. **Hint**: Remember that linear molecules with symmetrical bonds often have zero dipole moments. ### Conclusion After analyzing all the molecules: - **CH4**: Zero dipole moment - **H2O**: Non-zero dipole moment - **BF3**: Zero dipole moment - **CO2**: Zero dipole moment The only molecule that possesses a dipole moment is **H2O**. **Final Answer**: The molecule possessing a dipole moment is **H2O**.
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Knowledge Check

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    A
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    B
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    C
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    D
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    A
    B
    C
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    D
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    A
    ` 2,2 -` dimethylpropane
    B
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    C
    trans` -2-` pentene
    D
    ` 2, 2, 3, 3 -`tetramethylbutane
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