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The no.of chloride ions co-ordinated to ...

The no.of chloride ions co-ordinated to `Fe^(+3)` ion is hydrated `FeCl_3. 6H_2O`

Text Solution

Verified by Experts

The correct Answer is:
2
`[Fe(H_2O)_4Cl_2]Cl.2H_2O`
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Knowledge Check

  • The oxidation state of Fe in [Fe(CN)_6]^(-3) ion is

    A
    `+1`
    B
    `+2`
    C
    `+3`
    D
    Zero

  • Which will not give test of Fe^(3+) ions ?

    A
    `FeCl_(3)`
    B
    `K_(3)[Fe(CN)_(6)]`
    C
    `Fe_(4)[Fe(CN)_(6)]_(3)`
    D
    `K_(4)[Fe(CN)_(5)]`

  • The number of d-electrons in Fe^(2+) ion is

    A
    6
    B
    3
    C
    4
    D
    5

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    A quantity of 25.0 mL of solution containing both Fe^(2+) and Fe^(3+) ions is titrated with 25.0 mL of 0.0200 M KMnO_(4) (in dilute H_(2)SO_(4) ). As a result, all of the Fe^(2+) ions are oxidised to Fe^(3+) ions. Next 25 mL of the original solution is treated with Zn metal finally, the solution requires 40.0 mL of the same KMnO_(4) solution for oxidation to Fe^(3+) . MnO_(4)^(-)+5Fe^(2+)+8H^(+)toMn^(2+)+5Fe^(3+)+4H_(2)O Zinc aded in the second titration wil

    A quantity of 25.0 mL of solution containing both Fe^(2+) and Fe^(3+) ions is titrated with 25.0 mL of 0.0200 M KMnO_(4) (in dilute H_(2)SO_(4) ). As a result, all of the Fe^(2+) ions are oxidised to Fe^(3+) ions. Next 25 mL of the original solution is treated with Zn metal finally, the solution requires 40.0 mL of the same KMnO_(4) solution for oxidation to Fe^(3+) . MnO_(4)^(-)+5Fe^(2+)+8H^(+)toMn^(2+)+5Fe^(3+)+4H_(2)O IF 0.02 M K_(2)Cr_(2)O_(7) is used instead of 0.02 M KMnO_(4) its volume required in these titrations are respectively

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